(2-Butyne)hexacarbonyldicobalt

Base Information

Chemical Name:(2-Butyne)hexacarbonyldicobalt
CAS No.:37726-81-1
Molecular Formula:C10 H6 Co2 O6
Molecular Weight:340.14
Hs Code.:

Synonyms:Cobalt, [.mu.-[(2,3-.eta.:2,3-.eta.)-2-butyne]]hexacarbonyldi-, (Co-Co) (9CI);Cobalt, (2-butyne)hexacarbonyldi- (7CI);2-Butyne, cobalt complex;Hexacarbonyl(dimethylacetylene)dicobalt;

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Chemical Property of (2-Butyne)hexacarbonyldicobalt

Chemical Property:

Purity/Quality:

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Hazard Codes:

MSDS Files:: SDS file from LookChem

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Technology Process of (2-Butyne)hexacarbonyldicobalt

There total 4 articles about (2-Butyne)hexacarbonyldicobalt which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 24.0%

: 98419-59-1
nonacarbonyl(μ3-2-butyne)dicobaltruthenium(Co-Co,2Ru-Co)

: 1184-78-7
trimethylamine-N-oxide

: 536-74-3
phenylacetylene

: 37726-81-1
Co2(CO)6(μ-MeCCMe)

: RuCo₂*7CO*CH₃CCCH₃*2C₆H₅CCH=RuCo₂(CO)7(CH₃CCCH₃)(C₆H₅CCH)2

Guidance literature:: In dichloromethane; excess PhCCH added to soln. of RuCo2(CO)9(MeCCMe) in CH2Cl2 at -78°C, slow addn. of soln. of Me3NO in CH2Cl2 (the soln. becomes increasingly deeper red), warmed to room temp. (1h); evapn. (vac.), chromy. (silica gel, hexane/CH2Cl2);

Reference yield: 18.0%

: 503-17-3
dimethylacetylene

: 12154-91-5
(phenylacetylene)hexacarbonyldicobalt

: pentacarbonyl[μ-(1,2,3,4-η:1,4-η)-1,2dimethyl-4-phenyl-1,3-butadiene-1,4-diyl]dicobalt

: 37726-81-1
(2-butyne)hexacarbonyldicobalt

Guidance literature:: With trimethylamine N-oxide; In tetrahydrofuran; dichloromethane; N2-atmosphere; stirring (room temp., 45 - 90 min); chromy. (SiO2, hexane); elem. anal.;
DOI:10.1021/om980544y

Reference yield: 10.0%

: 673-32-5
1-Phenylprop-1-yne

: 98419-59-1
nonacarbonyl(μ3-2-butyne)dicobaltruthenium(Co-Co,2Ru-Co)

: 1184-78-7
trimethylamine-N-oxide

: 37726-81-1
Co2(CO)6(μ-MeCCMe)

: RuCo₂*7CO*CH₃CCC₆H₅*2CH₃CCCH₃=RuCo₂(CO)7(CH₃CCC₆H₅)(CH₃CCCH₃)2

Guidance literature:: In dichloromethane; excess MeCCPh added to soln. of RuCo2(CO)9(MeCCMe) in CH2Cl2 at -78°C, slow addn. of soln. of Me3NO in CH2Cl2 (the soln. becomes increasingly deeper red), warmed to room temp. (1h), short heating to 60°C; evapn. (vac.), chromy. (silica gel, hexane/CH2Cl2);