2,3,6,7,10,11-triphenylene-hexathiol, triphenylene-2,3,6,7,10,11-hexathiol, 2,3,6,7,10,11-triphenylenehexathiol, triphenylene hexathiol, THT

Base Information

• Chemical Name: 2,3,6,7,10,11-triphenylene-hexathiol, triphenylene-2,3,6,7,10,11-hexathiol, 2,3,6,7,10,11-triphenylenehexathiol, triphenylene hexathiol, THT
• CAS No.: 100077-38-1
• Molecular Formula: C18H12S6
• Molecular Weight: 420.689
• Mol file: 100077-38-1.mol

Synonyms:2,3,6,7,10,11-triphenylenehexathiol;triphenylene-2,3,6,7,10,11-hexathiol;

Chemical Property of 2,3,6,7,10,11-triphenylene-hexathiol, triphenylene-2,3,6,7,10,11-hexathiol, 2,3,6,7,10,11-triphenylenehexathiol, triphenylene hexathiol, THT

Chemical Property:

• Boiling Point: 726.4±55.0 °C(Predicted)
• PKA: 4.43±0.30(Predicted)
• PSA: 232.80000
• Density: 1.572±0.06 g/cm3(Predicted)
• LogP: 6.87840

Purity/Quality:

99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Use Description: 2,3,6,7,10,11-triphenylene-hexathiol, commonly known as THT, is a chemical compound with diverse applications in various fields. In the field of materials science and nanotechnology, THT is utilized as a building block for the construction of self-assembled monolayers on surfaces, particularly in the development of nanoscale electronic and optoelectronic devices. Its role is pivotal in creating stable and well-ordered molecular architectures, facilitating the fabrication of advanced materials and miniaturized electronic components. In addition, in analytical chemistry, THT can serve as a chelating agent for metal ions, aiding in the detection and quantification of various metals in environmental and analytical testing. Furthermore, in academic and scientific research, THT is a valuable tool for investigating molecular self-assembly, surface chemistry, and nanoscale phenomena, contributing to a deeper understanding of nanotechnology and materials science. Its multifaceted utility underscores its significance in advancing materials technology, analytical chemistry, and scientific exploration, where it plays a crucial role in the development of innovative materials, sensing technologies, and fundamental research.

Technology Process of 2,3,6,7,10,11-triphenylene-hexathiol, triphenylene-2,3,6,7,10,11-hexathiol, 2,3,6,7,10,11-triphenylenehexathiol, triphenylene hexathiol, THT

There total 4 articles about 2,3,6,7,10,11-triphenylene-hexathiol, triphenylene-2,3,6,7,10,11-hexathiol, 2,3,6,7,10,11-triphenylenehexathiol, triphenylene hexathiol, THT which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

2,3,6,7,10,11-hexa(methylthio)triphenylene → triphenylene-2,3,6,7,10,11-hexathiol (100077-38-1)

Guidance literature:

With lithium; In ammonia; at -78 ℃; for 3.5h; Inert atmosphere; liquid NH₃;

DOI:10.1021/ic400110z

Reference yield:

2,3,6,7,10,11-hexakis(butyrylthio)triphenylene (1586745-04-1) → triphenylene-2,3,6,7,10,11-hexathiol (100077-38-1)

Guidance literature:

With sodium hydroxide; In methanol; at 90 ℃; for 6h; Inert atmosphere; Schlenk technique;

DOI:10.1039/c5cc04476f

Reference yield:

hexasodium 2,3,6,7,10,11-triphenylenehexathiolate → triphenylene-2,3,6,7,10,11-hexathiol (100077-38-1)

Guidance literature:

With hydrogenchloride; In water;

DOI:10.1002/anie.201506048

upstream raw materials:

2,3,6,7,10,11-hexakis(butyrylthio)triphenylene

Refernces

• 1、 Mendecki, Lukasz,Ko, Michael,Zhang, Xiaoping,Meng, Zheng,Mirica, Katherine A.. "Porous Scaffolds for Electrochemically Controlled Reversible Capture and Release of Ethylene". . p. 17229 - 17232. Retrieved 2017.
• 2、 Dong, Renhao,Pfeffermann, Martin,Liang, Haiwei,Zheng, Zhikun,Zhu, Xiang,Zhang, Jian,Feng, Xinliang. "Large-Area, Free-Standing, Two-Dimensional Supramolecular Polymer Single-Layer Sheets for Highly Efficient Electrocatalytic Hydrogen Evolution". . p. 12058 - 12063. Retrieved 2015.