Silacyclopenta-2,4-diene, 1,1-dimethoxy-2,5-diphenyl-

Base Information

Chemical Name:Silacyclopenta-2,4-diene, 1,1-dimethoxy-2,5-diphenyl-
CAS No.:100840-05-9
Molecular Formula:C₁₈H₁₈O₂Si
Molecular Weight:294.425
Hs Code.:
DSSTox Substance ID:DTXSID70456732
Nikkaji Number:J1.085.219F
Wikidata:Q82279292
Mol file:100840-05-9.mol

Synonyms:Silacyclopenta-2,4-diene, 1,1-dimethoxy-2,5-diphenyl-;100840-05-9;DTXSID70456732;2,5-Diphenyl-1,1-dimethoxy-1-silacyclopenta-2,4-diene

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Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Silacyclopenta-2,4-diene, 1,1-dimethoxy-2,5-diphenyl-

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:4
Exact Mass:294.107606347
Heavy Atom Count:21
Complexity:375

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CO[Si]1(C(=CC=C1C2=CC=CC=C2)C3=CC=CC=C3)OC

Technology Process of Silacyclopenta-2,4-diene, 1,1-dimethoxy-2,5-diphenyl-

There total 2 articles about Silacyclopenta-2,4-diene, 1,1-dimethoxy-2,5-diphenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 21.0%

: 681-84-5
tetramethylorthosilicate

: (Z,Z')-1,4-diiodo-1,4-diphenylbuta-1,3-diene

: 100840-05-9
1,1-dimethoxy-2,5-diphenylsilycyclopentadiene

Guidance literature:: With n-butyllithium; In diethyl ether; -78 deg C to rt;
DOI:10.1021/jo981533h

Reference yield:

: 536-74-3
phenylacetylene

: 100840-05-9
1,1-dimethoxy-2,5-diphenylsilycyclopentadiene

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) Ti(O-i-Pr)4, i-PrMgCl, 2.) I₂ / 1.) ether, -70 deg C to -50 deg C, 2 h, 2.) -50 deg C to rt, 2 h

2: 21 percent / n-BuLi / diethyl ether / -78 deg C to rt

With titanium(IV) isopropylate; n-butyllithium; iodine; isopropylmagnesium chloride; In diethyl ether;
DOI:10.1021/jo981533h