Benzoic acid, 3,5-dinitro-, phenylmethyl ester

Base Information

• Chemical Name: Benzoic acid, 3,5-dinitro-, phenylmethyl ester
• CAS No.: 10478-07-6
• Molecular Formula: C14H10N2O6
• Molecular Weight: 302.243
• Mol file: 10478-07-6.mol

Synonyms:Benzoic acid,3,5-dinitro-,phenylmethyl ester;3,5-dinitro-benzoic acid benzyl ester;benzyl-3,5-dinitrobenzoate;3,5-dinitrobenzoate of benzyl alcohol;3,5-dinitro-benzoic acid,phenylmethyl ester;Benzoic acid, 3,5-dinitro-, phenylmethyl ester;3,5-Dinitro-benzoesaeure-benzyl-ester;

Chemical Property of Benzoic acid, 3,5-dinitro-, phenylmethyl ester

Chemical Property:

• PSA: 117.94000
• LogP: 3.90640

Purity/Quality:

98%,99%, ^*data from raw suppliers

3,5-DINITRO-BENZOIC ACID BENZYL ESTER Aldrich ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Benzoic acid, 3,5-dinitro-, phenylmethyl ester

There total 13 articles about Benzoic acid, 3,5-dinitro-, phenylmethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

3,5-dinitrobenzoic acid (99-34-3) + benzyl alcohol (100-51-6,185532-71-2) → 3,5-dinitrobenzoate of benzyl alcohol (10478-07-6)

Guidance literature:

With [bis(acetoxy)iodo]benzene; triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; at 20 ℃; for 16h; Inert atmosphere;

DOI:10.1055/s-0029-1219795

Reference yield: 93.0%

3,5-dinitrobenzoic acid (99-34-3) + toluene (108-88-3,15644-74-3,16713-13-6) → 3,5-dinitrobenzoate of benzyl alcohol (10478-07-6)

Guidance literature:

With tert.-butylhydroperoxide; 1-(n-butyl)pyridinium iodide; In water; at 80 ℃; for 8h;

DOI:10.1039/c7ra02788e

Reference yield: 88.0%

benzyl alcohol (100-51-6,185532-71-2) + 3,5-dinitrobenoyl chloride (99-33-2) → 3,5-dinitrobenzoate of benzyl alcohol (10478-07-6)

Guidance literature:

With potassium carbonate; sodium chloride; at 120 ℃; for 0.0333333h; under 3225.32 Torr; Microwave irradiation; Sealed tube; Green chemistry;

DOI:10.1080/00397911.2015.1078899

upstream raw materials:

benzyl chloride

benzyl alcohol

3,5-dinitrobenoyl chloride

3,5-dinitrobenzoic acid

Downstream raw materials:

benzyl 3,5-diaminobenzoate

Refernces

• 1、 Ghosh, Subhankar,Banerjee, Jeet,Ghosh, Rajat,Chattopadhyay, Shital K.. "A metal-free iodine-mediated conversion of hydroxamates to esters". . p. 1353 - 1360. Retrieved 2020/03/30.
• 2、 Chakraborty, Suchandra,Saha, Ahana,Basu, Kaushik,Saha, Chandan. "Solid-Phase Benzoylation of Phenols and Alcohols in Microwave Reactor: An Ecofriendly Protocol". supporting information. p. 2331 - 2343. Retrieved 2015/10/12.