Technology Process of Rhenium, trichlorooxobis[tris(4-fluorophenyl)phosphine]-
There total 1 articles about Rhenium, trichlorooxobis[tris(4-fluorophenyl)phosphine]- which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
HCl;
In
acetic acid;
aq. acetic acid; addn. of concd. HCl to HReO4, addn. of soln. to phosphine in acetic acid, stirred for 1 h at ambient temp.; filtered, washed with acetic acid and ether, dried under vac.; elem. anal.;
DOI:10.1021/ja00253a017
- Guidance literature:
-
In
diethyl ether;
under N2, stirred for 1 h at ambient temp.; cooled to 0°C under N2, addn. of a NaOH soln. and water, filtered, washed with ether, filtrates concd., addn. of ether, chilling, filtered, washed with ether, dried; elem. anal.;
DOI:10.1021/ja00253a017
- Guidance literature:
-
With
lithium aluminium hydride;
In
diethyl ether;
ReOCl3(P(p-C6H4F)3)2 was was placed under vac. for 1 h, ether was vac.transferred into the flask, LiAlH4 was added over 10 min, kept for 30 min; filtered, filtrate was evapd., excess LiAlH4 was decompd. by wet CH2Cl2 (-40°C) and H2O (0°C) under N2, mixt. was filtered, cooled by addn. of liq. N2, decanted, evapd. (10**-3 Torr), residue was washed with Et2O under N2, dried under vac.;
