2,4-Decadienoic acid, methyl ester, (Z,E)-

Base Information

• Chemical Name: 2,4-Decadienoic acid, methyl ester, (Z,E)-
• CAS No.: 108965-84-0
• Molecular Formula: C11H18O2
• Molecular Weight: 182.263
• Mol file: 108965-84-0.mol

Synonyms:2,4-Decadienoic acid, methyl ester, (Z,E)-;.(2Z,4E)-methyl decadionate;.Deca-2c,4t-diensaeure-methylester;.deca-2c,4t-dienoic acid methyl ester;(2Z,4E)-methyl-decadienoate;.methyl (2Z,4E)-decadienoate;.(Z,E)-2,4-decadienoic acid,methyl ester;

Chemical Property of 2,4-Decadienoic acid, methyl ester, (Z,E)-

Chemical Property:

• Refractive Index: 1.4876 (estimate)
• Boiling Point: 255.67°C (rough estimate)
• PSA: 26.30000
• Density: 0.9131
• LogP: 2.85210

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2,4-Decadienoic acid, methyl ester, (Z,E)-

There total 8 articles about 2,4-Decadienoic acid, methyl ester, (Z,E)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(+/-)-methyl 3,4-decadienoate (1360440-03-4) → methyl (2Z,4Z)-2,4-decadienoate (108965-86-2) + methyl (2Z,4E)-2,4-decadienoate (108965-84-0) + methyl (2E,4Z)-deca-2,4-dienoate (4493-42-9) + methyl (2E,4E)-decadienoate (7328-33-8)

Guidance literature:

With aluminum oxide; In o-xylene; at 160 ℃; for 2h; Inert atmosphere;

DOI:10.1016/j.tet.2011.12.064

Reference yield:

acrylic acid methyl ester (292638-85-8,9003-21-8,96-33-3) + 1-iodo-1-heptene → methyl (2Z,4Z)-2,4-decadienoate (108965-86-2) + methyl (2Z,4E)-2,4-decadienoate (108965-84-0) + methyl (2E,4Z)-deca-2,4-dienoate (4493-42-9) + methyl (2E,4E)-decadienoate (7328-33-8)

Guidance literature:

With tetrabutyl-ammonium chloride; palladium diacetate; potassium carbonate; In N,N-dimethyl-formamide; at 20 ℃; for 1h; Inert atmosphere;

DOI:10.1016/j.tet.2011.12.064

Reference yield:

methyl deca-(2Z)-en-4-ynoate (118793-68-3) → methyl (2Z,4Z)-2,4-decadienoate (108965-86-2) + methyl (2Z,4E)-2,4-decadienoate (108965-84-0) + methyl (2E,4Z)-deca-2,4-dienoate (4493-42-9) + methyl (2E,4E)-decadienoate (7328-33-8)

Guidance literature:

With quinoline; hydrogen; Lindlar's catalyst; In hexane; Yield given;

DOI:10.1016/S0040-4020(01)81705-1

upstream raw materials:

methyl (2E,4E)-decadienoate

1-Heptyne

methyl (Z)-3-bromoacrylate

methyl deca-(2Z)-en-4-ynoate

Downstream raw materials:

Methyl decanoate

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