Carbamodithioic acid, methyl(phenylmethyl)-, phenyl ester

Base Information

• Chemical Name: Carbamodithioic acid, methyl(phenylmethyl)-, phenyl ester
• CAS No.: 109720-09-4
• Molecular Formula: C15H15NS2
• Molecular Weight: 273.41600
• Mol file: 109720-09-4.mol

Synonyms:S-phenyl N-benzyl-N-methyldithiocarbamate;Carbamodithioic acid,methyl(phenylmethyl)-,phenyl ester;

Chemical Property of Carbamodithioic acid, methyl(phenylmethyl)-, phenyl ester

Chemical Property:

• PSA: 60.63000
• LogP: 4.19560

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Carbamodithioic acid, methyl(phenylmethyl)-, phenyl ester

There total 5 articles about Carbamodithioic acid, methyl(phenylmethyl)-, phenyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

diphenyliodonium chloride (1483-72-3) + N-benzyl-N-methylcarbamodithioate sodium salt (57802-74-1) → S-phenyl N-benzyl-N-methyldithiocarbamate (109720-09-4)

Guidance literature:

In tert-butyl alcohol; at 70 ℃; for 5h;

DOI:10.1021/jo00227a032

Reference yield: 75.0%

carbon disulfide (75-15-0,12122-00-8) + Diphenyliodonium triflate (66003-76-7) + benzyl-methyl-amine (103-67-3) → S-phenyl N-benzyl-N-methyldithiocarbamate (109720-09-4)

Guidance literature:

carbon disulfide; benzyl-methyl-amine; In dichloromethane; at 20 ℃; for 0.0833333h; Sealed tube;

Diphenyliodonium triflate; In dichloromethane; at 20 ℃; for 2h; Sealed tube;

DOI:10.1021/acs.orglett.1c02220

Reference yield: 72.0%

carbon disulfide (75-15-0,12122-00-8) + 2-(trimethylsilyl)phenyl trifluoromethanesulfonate (88284-48-4) + benzyl-methyl-amine (103-67-3) → S-phenyl N-benzyl-N-methyldithiocarbamate (109720-09-4)

Guidance literature:

carbon disulfide; benzyl-methyl-amine; With potassium fluoride; 18-crown-6 ether; In tetrahydrofuran; for 0.0333333h; Sealed tube; Inert atmosphere;

2-(trimethylsilyl)phenyl trifluoromethanesulfonate; In tetrahydrofuran; at 25 ℃; for 12h; Inert atmosphere; Sealed tube;

DOI:10.1021/acs.orglett.1c03378

upstream raw materials:

diphenyliodonium chloride

N-benzyl-N-methylcarbamodithioate sodium salt

sodium thiophenolate

benzyl-methyl-amine

Refernces

• 1、 Bhattacharjee, Subrata,Deswal, Shiksha,Manoj, Niket,Jindal, Garima,Biju, Akkattu T.. "Aryne Three-Component Coupling Involving CS2for the Synthesis of S-Aryl Dithiocarbamates". supporting information. p. 9083 - 9088. Retrieved 2021/11/30.
• 2、 Chen, Zhen-Chu,Jin, You-Yuan,Stang, Peter J.. "Polyvalent Iodine in Synthesis. 2. A New Method for the Preparation of Aryl Esters of Dithiocarbamic Acids". . p. 4117 - 4118. Retrieved 2007/10/02.