Phenyl{bis[(phenylsulfanyl)methyl]}phosphane

Base Information

Chemical Name:Phenyl{bis[(phenylsulfanyl)methyl]}phosphane
CAS No.:110139-86-1
Molecular Formula:C20H19PS2
Molecular Weight:354.46900
Hs Code.:
DSSTox Substance ID:DTXSID40546472
Wikidata:Q82424321
Mol file:110139-86-1.mol

Synonyms:110139-86-1;Phenyl{bis[(phenylsulfanyl)methyl]}phosphane;DTXSID40546472

Suppliers and Price of Phenyl{bis[(phenylsulfanyl)methyl]}phosphane

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Phenyl{bis[(phenylsulfanyl)methyl]}phosphane

Chemical Property:

PSA：64.19000
LogP:6.29340
XLogP3:6.1
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:7
Exact Mass:354.06657995
Heavy Atom Count:23
Complexity:283

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:C1=CC=C(C=C1)P(CSC2=CC=CC=C2)CSC3=CC=CC=C3

Technology Process of Phenyl{bis[(phenylsulfanyl)methyl]}phosphane

There total 1 articles about Phenyl{bis[(phenylsulfanyl)methyl]}phosphane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 7205-91-6
phenylthiomethyl chloride

: 644-97-3
Dichlorophenylphosphine

: 110139-86-1
bis(phenylthiomethyl)phenylphosphine

Guidance literature:: With magnesium; Yield given. Multistep reaction; 1.) THF; 2.) THF, r.t., 5 h;
DOI:10.1246/bcsj.59.3293

Reference yield: 80.0%

: 110139-86-1
bis(phenylthiomethyl)phenylphosphine

: 51334-63-5
bis(phenylsulfinylmethyl)phenylphosphine oxide

Guidance literature:: With dihydrogen peroxide; In water; acetic acid; 1.) 0 deg C, 1 h; 2.) r.t., 0.5 h;
DOI:10.1246/bcsj.59.3293

Reference yield:

: 110139-86-1
bis(phenylthiomethyl)phenylphosphine

: C₂₀H₁₇O₃PS₂

Guidance literature:: Multi-step reaction with 3 steps

1: 80 percent / H₂O₂ / H₂O; acetic acid / 1.) 0 deg C, 1 h; 2.) r.t., 0.5 h

2: 60 percent / bromine, N-bromosuccinimide, pyridine / CH₂Cl₂ / 3 h / Ambient temperature

3: 3 percent / triethylamine / tetrahydrofuran / 12 h / Ambient temperature

With pyridine; N-Bromosuccinimide; dihydrogen peroxide; bromine; triethylamine; In tetrahydrofuran; dichloromethane; water; acetic acid;
DOI:10.1246/bcsj.59.3293