Triphenylundecylphosphonium bromide

Base Information

• Chemical Name: Triphenylundecylphosphonium bromide
• CAS No.: 60669-22-9
• Molecular Formula: C29H38 P . Br
• Molecular Weight: 497.498
• Hs Code.: 2931900090
• European Community (EC) Number: 262-363-3
• DSSTox Substance ID: DTXSID50976100
• Mol file: 60669-22-9.mol

Synonyms:60669-22-9;Triphenylundecylphosphonium bromide;EINECS 262-363-3;n-Undecyl triphenylphosponium bromide;triphenyl(undecyl)phosphanium bromide;C29H38P.Br;SCHEMBL2446607;DTXSID50976100;AELWOFMTABHNQJ-UHFFFAOYSA-M;Undecyltriphenylphosphonium bromide;Triphenyl(undecyl)phosphoniumbromide;undecyl triphenylphosphonium bromide;n-undecyl-triphenylphosphoniumbromide;Triphenyl(undecyl)phosphonium bromide;undecyl-triphenyl-phosphonium bromide;n-undecyl-triphenylphosphonium bromide;AKOS037621371;(1-UNDECYL)TRIPHENYLPHOSPHONIUM BROMIDE

Chemical Property of Triphenylundecylphosphonium bromide

Chemical Property:

• PSA: 13.59000
• LogP: 4.51530
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 13
• Exact Mass: 496.18945
• Heavy Atom Count: 31
• Complexity: 367

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Statements: R36/37/38:Irritating to eyes, respiratory system and skin.
• Safety Statements: S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.; S36:Wear suitable prot

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCCCCCCC[P+](C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3.[Br-]

Technology Process of Triphenylundecylphosphonium bromide

There total 3 articles about Triphenylundecylphosphonium bromide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

bromoundecane (693-67-4) + triphenylphosphine (603-35-0) → n-undecyltriphenylphosphonium bromide (60669-22-9)

Guidance literature:

at 100 ℃; for 12h;

DOI:10.1016/S0040-4020(01)85638-6

Reference yield:

→ n-undecyltriphenylphosphonium bromide (60669-22-9)

Guidance literature:

In toluene; for 72h; Reflux; Inert atmosphere;

Reference yield:

→ methyl 4-(2-tridecenyl)pyrrole-2-carboxylate + n-undecyltriphenylphosphonium bromide (60669-22-9)

Guidance literature:

upstream raw materials:

bromoundecane

triphenylphosphine

Downstream raw materials:

(5R*,6S*)-6-hydroxyhexadecan-5-olide

racemic erythro 6-acetoxy-5-hexadecanolide

(Z) 3-(1-Dodecenyl)phenol

C₂₉H₄₄O₄

Refernces

• 1、 Liu, Jun,Bandyopadhyay, Indrajit,Zheng, Lei,Khdour, Omar M.,Hecht, Sidney M.. "Antiferroptotic Activity of Phenothiazine Analogues: A Novel Therapeutic Strategy for Oxidative Stress Related Disease". supporting information. p. 2165 - 2173. Retrieved 2020/12/17.
• 2、 -. "NOVEL GLYCINE TRANSPORT INHIBITORS FOR THE TREATMENT OF PAIN". Page/Page column 51; 52. . Retrieved 2018/08/12.