9H-Thioxanthen-9-one, 1-[[2-(dimethylamino)ethyl]amino]-7-[[(1,1-dimethylethyl)diphenylsilyl]oxy ]-4-(hydroxymethyl)-

Base Information

Chemical Name:9H-Thioxanthen-9-one, 1-[[2-(dimethylamino)ethyl]amino]-7-[[(1,1-dimethylethyl)diphenylsilyl]oxy ]-4-(hydroxymethyl)-
CAS No.:111324-55-1
Molecular Formula:C34H38N2O3SSi
Molecular Weight:582.839
Hs Code.:
Mol file:111324-55-1.mol

Synonyms:

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Chemical Property of 9H-Thioxanthen-9-one, 1-[[2-(dimethylamino)ethyl]amino]-7-[[(1,1-dimethylethyl)diphenylsilyl]oxy ]-4-(hydroxymethyl)-

Chemical Property:

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Technology Process of 9H-Thioxanthen-9-one, 1-[[2-(dimethylamino)ethyl]amino]-7-[[(1,1-dimethylethyl)diphenylsilyl]oxy ]-4-(hydroxymethyl)-

There total 8 articles about 9H-Thioxanthen-9-one, 1-[[2-(dimethylamino)ethyl]amino]-7-[[(1,1-dimethylethyl)diphenylsilyl]oxy ]-4-(hydroxymethyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 111324-54-0
1-<<2-(dimethylamino)ethyl>amino>-7-<(tert-butyldiphenylsilyl)oxy>-9-oxo-9H-thioxanthene-4-carboxaldehyde

: 111324-55-1
1-<<2-(dimethylamino)ethyl>amino>-7-<(tert-butyldiphenylsilyl)oxy>-4-(hydroxymethyl)-9H-thioxanthen-9-one

Guidance literature:: With sodium tetrahydroborate; In methanol; diethyl ether; for 2h; Ambient temperature;
DOI:10.1021/jm00396a040

Reference yield:

: 86456-31-7
1-<<2-(dimethylamino)ethyl>amino>-7-hydroxy-9H-thioxanthen-9-one

: 111324-55-1
1-<<2-(dimethylamino)ethyl>amino>-7-<(tert-butyldiphenylsilyl)oxy>-4-(hydroxymethyl)-9H-thioxanthen-9-one

Guidance literature:: Multi-step reaction with 6 steps

1: 87 percent / pyridine / 0.5 h / Ambient temperature

2: 66 percent / aq. AcOH / 72 h / 80 °C

3: 83 percent / MnO₂ / CH₂Cl₂ / 2 h / Heating

4: aq. KOH / ethanol / 1 h / Heating

5: 93 percent / imidazole / dimethylformamide / 36 h / Ambient temperature

6: 1.6 g / NaBH₄ / methanol; diethyl ether / 2 h / Ambient temperature

With 1H-imidazole; manganese(IV) oxide; potassium hydroxide; sodium tetrahydroborate; acetic acid; In pyridine; methanol; diethyl ether; ethanol; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/jm00396a040

Reference yield:

: 86456-11-3
1-<<2-(dimethylamino)ethyl>amino>-7-hydroxy-9-oxo-9H-thioxanthene-4-carboxaldehyde

: 111324-55-1
1-<<2-(dimethylamino)ethyl>amino>-7-<(tert-butyldiphenylsilyl)oxy>-4-(hydroxymethyl)-9H-thioxanthen-9-one

Guidance literature:: Multi-step reaction with 2 steps

1: 93 percent / imidazole / dimethylformamide / 36 h / Ambient temperature

2: 1.6 g / NaBH₄ / methanol; diethyl ether / 2 h / Ambient temperature

With 1H-imidazole; sodium tetrahydroborate; In methanol; diethyl ether; N,N-dimethyl-formamide;
DOI:10.1021/jm00396a040