2,7-Nonadienoic acid, 7-methyl-3-(phenylthio)-9-[(tetrahydro-2H-pyran-2-yl)oxy]-, methyl ester, (Z,E)-

Base Information

Chemical Name:2,7-Nonadienoic acid, 7-methyl-3-(phenylthio)-9-[(tetrahydro-2H-pyran-2-yl)oxy]-, methyl ester, (Z,E)-
CAS No.:111350-99-3
Molecular Formula:C₂₂H₃₀O₄S
Molecular Weight:390.544
Hs Code.:
Mol file:111350-99-3.mol

Synonyms:

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Chemical Property of 2,7-Nonadienoic acid, 7-methyl-3-(phenylthio)-9-[(tetrahydro-2H-pyran-2-yl)oxy]-, methyl ester, (Z,E)-

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Technology Process of 2,7-Nonadienoic acid, 7-methyl-3-(phenylthio)-9-[(tetrahydro-2H-pyran-2-yl)oxy]-, methyl ester, (Z,E)-

There total 18 articles about 2,7-Nonadienoic acid, 7-methyl-3-(phenylthio)-9-[(tetrahydro-2H-pyran-2-yl)oxy]-, methyl ester, (Z,E)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 105-87-3,8022-83-1
3,7-dimethyl-2E,6-octadien-1-yl acetate

: 111350-99-3
Methyl (2Z,7E)-7-Methyl-3-(phenylthio)-9-(tetrahydropyranyloxy)-2,7-nonadienoate

Guidance literature:: Multi-step reaction with 9 steps

1: N-Methyl-morpholine N-oxide monohydrate, osmium tetraoxide / acetone; tetrahydrofuran; H₂O / 1). 18 h, room temperature, 2) 12 h, 50 deg C

2: Sodium periodate / dioxane; H₂O / 1.5 h / 0 - 5 °C

3: Lithium tri-tert-butoxyaluminium hydride / tetrahydrofuran / 0.17 h / Ambient temperature

4: 99 percent / pyridine / 3 h / 0 - 5 °C

5: 92 percent / Lithium bromide, sodium hydrogen carbonate / acetone / 72 h / Ambient temperature

6: 1.) Li, 2.) liq. NH₃ / 2.) Dimethyl sulfoxide, reflux, 2h; r. t., overnight

7: 99.5 percent / p-Toluenesulfonic acid / CH₂Cl₂ / 3 h / Ambient temperature

8: 1) 1.6 N n-Buthyllithium in hexane / 1) THF, 0-5 deg C, 40 min, 2) THF, -60 deg C to 0 deg C

9: 1) Sodium hydroxide / 1) CH₃OH, 2) room temperature, 2,5 h, CH₃OH

With sodium hydroxide; sodium periodate; osmium(VIII) oxide; n-butyllithium; lithium tri(t-butoxy)aluminum hydride; ammonia; lithium; sodium hydrogencarbonate; toluene-4-sulfonic acid; 4-methylmorpholine N-oxide; lithium bromide; In tetrahydrofuran; 1,4-dioxane; pyridine; dichloromethane; water; acetone;

Reference yield:

: 105-87-3,8022-83-1
3,7-dimethyl-2E,6-octadien-1-yl acetate

: 111350-99-3
(2E,7E)-7-Methyl-3-phenylsulfanyl-9-(tetrahydro-pyran-2-yloxy)-nona-2,7-dienoic acid methyl ester

Guidance literature:: Multi-step reaction with 9 steps

1: N-Methyl-morpholine N-oxide monohydrate, osmium tetraoxide / acetone; tetrahydrofuran; H₂O / 1). 18 h, room temperature, 2) 12 h, 50 deg C

2: Sodium periodate / dioxane; H₂O / 1.5 h / 0 - 5 °C

3: Lithium tri-tert-butoxyaluminium hydride / tetrahydrofuran / 0.17 h / Ambient temperature

4: 99 percent / pyridine / 3 h / 0 - 5 °C

5: 92 percent / Lithium bromide, sodium hydrogen carbonate / acetone / 72 h / Ambient temperature

6: 1.) Li, 2.) liq. NH₃ / 2.) Dimethyl sulfoxide, reflux, 2h; r. t., overnight

7: 99.5 percent / p-Toluenesulfonic acid / CH₂Cl₂ / 3 h / Ambient temperature

8: 1) 1.6 N n-Buthyllithium in hexane / 1) THF, 0-5 deg C, 40 min, 2) THF, -60 deg C to 0 deg C

9: 1) Sodium hydroxide / 1) CH₃OH, 2) room temperature, 2,5 h, CH₃OH

With sodium hydroxide; sodium periodate; osmium(VIII) oxide; n-butyllithium; lithium tri(t-butoxy)aluminum hydride; ammonia; lithium; sodium hydrogencarbonate; toluene-4-sulfonic acid; 4-methylmorpholine N-oxide; lithium bromide; In tetrahydrofuran; 1,4-dioxane; pyridine; dichloromethane; water; acetone;

Reference yield:

: 35334-60-2
(E)-6-acetoxy-4-methyl-4-hexenal

: 111350-99-3
Methyl (2Z,7E)-7-Methyl-3-(phenylthio)-9-(tetrahydropyranyloxy)-2,7-nonadienoate

Guidance literature:: Multi-step reaction with 7 steps

1: Lithium tri-tert-butoxyaluminium hydride / tetrahydrofuran / 0.17 h / Ambient temperature

2: 99 percent / pyridine / 3 h / 0 - 5 °C

3: 92 percent / Lithium bromide, sodium hydrogen carbonate / acetone / 72 h / Ambient temperature

4: 1.) Li, 2.) liq. NH₃ / 2.) Dimethyl sulfoxide, reflux, 2h; r. t., overnight

5: 99.5 percent / p-Toluenesulfonic acid / CH₂Cl₂ / 3 h / Ambient temperature

6: 1) 1.6 N n-Buthyllithium in hexane / 1) THF, 0-5 deg C, 40 min, 2) THF, -60 deg C to 0 deg C

7: 1) Sodium hydroxide / 1) CH₃OH, 2) room temperature, 2,5 h, CH₃OH

With sodium hydroxide; n-butyllithium; lithium tri(t-butoxy)aluminum hydride; ammonia; lithium; sodium hydrogencarbonate; toluene-4-sulfonic acid; lithium bromide; In tetrahydrofuran; pyridine; dichloromethane; acetone;