Naphthalene, 2-bromo-6-(methoxymethoxy)-

Base Information

• Chemical Name: Naphthalene, 2-bromo-6-(methoxymethoxy)-
• CAS No.: 111359-62-7
• Molecular Formula: C12H11BrO2
• Molecular Weight: 267.11900
• Mol file: 111359-62-7.mol

Synonyms:Naphthalene,2-bromo-6-(methoxymethoxy);

Chemical Property of Naphthalene, 2-bromo-6-(methoxymethoxy)-

Chemical Property:

• PSA: 18.46000
• LogP: 3.58500

Purity/Quality:

99% ^*data from raw suppliers

2-Bromo-6-(methoxymethoxy)naphthalene 95% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Naphthalene, 2-bromo-6-(methoxymethoxy)-

There total 2 articles about Naphthalene, 2-bromo-6-(methoxymethoxy)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

6-bromo-naphthalen-2-ol (15231-91-1) + chloromethyl methyl ether (107-30-2) → 6-Bromo-2-methoxymethyleneoxynaphthalene (111359-62-7)

Guidance literature:

With N-ethyl-N,N-diisopropylamine; at 0 - 20 ℃;

DOI:10.1039/c9cc00611g

Reference yield:

6-bromo-naphthalen-2-ol (15231-91-1) + bromethyl methyl ether (13057-17-5) → 6-Bromo-2-methoxymethyleneoxynaphthalene (111359-62-7)

Guidance literature:

With sodium hydroxide; In N-methyl-acetamide; dichloromethane;

upstream raw materials:

6-bromo-naphthalen-2-ol

bromethyl methyl ether

chloromethyl methyl ether

Refernces

• 1、 -. "SELECTIVE NON-CYCLIC NUCLEOTIDE ACTIVATORS FOR THE CAMP SENSOR EPAC1". Page/Page column 00165; 00166; 00198; 00215. . Retrieved 2021/09/26.
• 2、 Xia, Yu,Bao, Qiao-Fei,Li, Yuke,Wang, Li-Jing,Zhang, Bo-Sheng,Liu, Hong-Chao,Liang, Yong-Min. "Ligand-controlled regiodivergent π-allyl palladium catalysis enables a switch between [3+2] and [3+3] cycloadditions". supporting information. p. 4675 - 4678. Retrieved 2019/05/02.