Benzenesulfinic acid, 1-methylethyl ester, (S)-

Base Information

• Chemical Name: Benzenesulfinic acid, 1-methylethyl ester, (S)-
• CAS No.: 111698-34-1
• Molecular Formula: C₉H₁₂O₂S
• Molecular Weight: 184.259
• Mol file: 111698-34-1.mol

Synonyms:

Chemical Property of Benzenesulfinic acid, 1-methylethyl ester, (S)-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Benzenesulfinic acid, 1-methylethyl ester, (S)-

There total 59 articles about Benzenesulfinic acid, 1-methylethyl ester, (S)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

tert-butylisonitrile (119072-55-8,7188-38-7) + S-(4-chlorophenyl)benzene thiosulfonate (1213-40-7) → (+/-)S-isopropyl phenylsulfinate (111698-34-1,114376-03-3,126188-13-4,52736-48-8) + S-(4-chlorophenyl) tert-butylcarbamothioate

Guidance literature:

With sodium iodide; In isopropyl alcohol; at 30 ℃; for 4h;

DOI:10.1021/acs.orglett.6b01023

Reference yield: 99.0%

tert-butylisonitrile (119072-55-8,7188-38-7) + benzenethiosulfonic acid S-(4-methoxyphenyl) ester (1146-48-1) → (+/-)S-isopropyl phenylsulfinate (111698-34-1,114376-03-3,126188-13-4,52736-48-8) + S-(4-methoxyphenyl) tert-butylcarbamothioate

Guidance literature:

With sodium iodide; In isopropyl alcohol; at 30 ℃; for 4h;

DOI:10.1021/acs.orglett.6b01023

Reference yield: 98.0%

S-Phenyl benzenethiosulfonate (1212-08-4) + tert-butylisonitrile (119072-55-8,7188-38-7) → S-phenyl tert-butylcarbamothioate (56741-04-9) + (+/-)S-isopropyl phenylsulfinate (111698-34-1,114376-03-3,126188-13-4,52736-48-8)

Guidance literature:

With sodium iodide; In isopropyl alcohol; at 30 ℃; for 4h; Reagent/catalyst; Solvent; Time; Temperature;

DOI:10.1021/acs.orglett.6b01023

upstream raw materials:

isopropyl alcohol

thiophenol

benzenesulphinyl chloride

S-methyl benzenethiosulfinate

Downstream raw materials:

(+/-)_S-cyclohexylidene(phenylsulfinyl)methane

<(1-Cyclohexenyl)methyl>-phenyl-sulfoxid

(+/-)_S-(E)-2-(4-chlorophenyl)-1-(phenylsulfinyl)ethene

(+/-)_S-(Z)-2-(4-chlorophenyl)-1-(phenylsulfinyl)ethene