9,11-Tridecadienoic acid, 13-hydroxy-, 1,1-dimethylethyl ester, (E,Z)-

Base Information

• Chemical Name: 9,11-Tridecadienoic acid, 13-hydroxy-, 1,1-dimethylethyl ester, (E,Z)-
• CAS No.: 111699-13-9
• Molecular Formula: C17H30O3
• Molecular Weight: 282.423
• Mol file: 111699-13-9.mol

Synonyms:

Chemical Property of 9,11-Tridecadienoic acid, 13-hydroxy-, 1,1-dimethylethyl ester, (E,Z)-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 9,11-Tridecadienoic acid, 13-hydroxy-, 1,1-dimethylethyl ester, (E,Z)-

There total 1 articles about 9,11-Tridecadienoic acid, 13-hydroxy-, 1,1-dimethylethyl ester, (E,Z)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 39.0%

1-ethyl 13-t-butyl (2E,4Z)-2,4-tridecadiene-1,13-dioate → 1,13-tridecanediol (13362-52-2) + (2E,4Z)-Trideca-2,4-diene-1,13-diol (76934-45-7) + t-butyl (9Z,11E)-13-hydroxy-9,11-tridecadienoate (111699-13-9)

Guidance literature:

With diisobutylaluminium hydride; In tetrahydrofuran; hexane; at -15 ℃; for 0.5h;

DOI:10.1246/bcsj.60.1103

Reference yield:

t-butyl (9Z,11E)-13-hydroxy-9,11-tridecadienoate (111699-13-9) → eleostearic acid (506-23-0,544-72-9,544-73-0,3884-88-6,4337-71-7,13296-76-9,24022-76-2,146525-62-4)

Guidance literature:

Multi-step reaction with 3 steps

1: 93 percent / activated MnO₂ / petroleum ether / 2 h / 25 °C

2: 1.) Mg / 1.) THF, 2 h, 2.) THF, -15 deg C, 2 h

3: 54 percent / Me₃SiCl, NaI / acetonitrile / 3 h / 25 °C

With manganese(IV) oxide; chloro-trimethyl-silane; magnesium; sodium iodide; In acetonitrile; Petroleum ether;

DOI:10.1246/bcsj.60.1103

Downstream raw materials:

eleostearic acid