9,10-Dihydro-9,10-ethanoanthracen-11-amine

Base Information

• Chemical Name: 9,10-Dihydro-9,10-ethanoanthracen-11-amine
• CAS No.: 6372-65-2
• Molecular Formula: C16H15N
• Molecular Weight: 221.302
• NSC Number: 55265
• DSSTox Substance ID: DTXSID60993540
• Nikkaji Number: J275.776A
• ChEMBL ID: CHEMBL430935
• Mol file: 6372-65-2.mol

Synonyms:9,10-dihydro-9,10-ethanoanthracen-11-amine;CHEMBL430935;6372-65-2;NSC55265;SCHEMBL7763035;DTXSID60993540;BDBM50111532;NSC-55265;72720-40-2;EN300-37451245;tetracyclo[6.6.2.0^{2,7}.0^{9,14}]hexadeca-2,4,6,9,11,13-hexaen-15-amine;tetracyclo[6.6.2.02,7.09,14]hexadeca-2,4,6,9(14),10,12-hexaen-15-amine

Chemical Property of 9,10-Dihydro-9,10-ethanoanthracen-11-amine

Chemical Property:

• Vapor Pressure: 3.95E-14mmHg at 25°C
• Boiling Point: 595.1°C at 760 mmHg
• Flash Point: 313.7°C
• Density: 1.35g/cm³
• XLogP3: 2.7
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 221.120449483
• Heavy Atom Count: 17
• Complexity: 276

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1C(C2C3=CC=CC=C3C1C4=CC=CC=C24)N

Technology Process of 9,10-Dihydro-9,10-ethanoanthracen-11-amine

There total 8 articles about 9,10-Dihydro-9,10-ethanoanthracen-11-amine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

9,10-dihydro-9,10-ethanoanthracen-11-one oxime (77154-92-8) → 9,10-dihydro-9,10-ethano-anthracen-11-ylamine (6372-65-2)

Guidance literature:

With hydrogen; 10percent Pd/C; In methanol; under 2844.39 Torr;

DOI:10.1021/jm010354g

Reference yield: 60.0%

hydroxyimino-11 ethano-9,10-dihydro-9,10 anthracene (77154-92-8) → amino-11 ethano-9,10 dihydro-9,10 anthracene (6372-65-2)

Guidance literature:

With lithium aluminium tetrahydride; In diethyl ether; for 48h; Heating;

DOI:10.1016/0040-4020(80)80229-8

Reference yield:

→ 9,10-dihydro-9,10-ethano-anthracen-11-ylamine (6372-65-2)

Guidance literature:

With ethanol; platinum; Hydrogenation;

DOI:10.1021/ja01582a053

upstream raw materials:

9,10-dihydro-9,10-ethanoanthracen-11-one oxime

(9,10-dihydro-9,10-ethano-anthracen-11-yl)-carbamic acid ethyl ester

hydroxyimino-11 ethano-9,10-dihydro-9,10 anthracene

9,10-dihydro-9,10-ethanoanthracen-11-one

Downstream raw materials:

anthracene

vinylamine