Stannane, trimethyl[2-phenyl-1-(trimethylplumbyl)-1-propenyl]-, (Z)-

Base Information

• Chemical Name: Stannane, trimethyl[2-phenyl-1-(trimethylplumbyl)-1-propenyl]-, (Z)-
• CAS No.: 112166-81-1
• Molecular Formula: C₁₅H₂₆PbSn
• Molecular Weight: 532.281

Synonyms:

Chemical Property of Stannane, trimethyl[2-phenyl-1-(trimethylplumbyl)-1-propenyl]-, (Z)-

Chemical Property:

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Technology Process of Stannane, trimethyl[2-phenyl-1-(trimethylplumbyl)-1-propenyl]-, (Z)-

There total 2 articles about Stannane, trimethyl[2-phenyl-1-(trimethylplumbyl)-1-propenyl]-, (Z)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(CH3)(C6H5)CC(Sn(CH3)3)2 (103670-46-8) + trimethyllead chloride (1520-78-1) → C6H5(CH3)CC(Sn(CH3)3)Pb(CH3)3 (112166-80-0,112166-81-1) + C6H5(CH3)CC(Sn(CH3)3)Pb(CH3)3 (112166-80-0,112166-81-1)

Guidance literature:

With methyllithium; In 1,2-dimethoxyethane; equimolar mixt. of distannylalkene and MeLi in DME was stirred at -78°C for 1-2 h under Ar, added to 1 equiv of Me3PbCl in DME, stirred for 1 h at -78°C, allowed to warm to room temp.; E/Z ratio 80:20 according to (1)H NMR data; water was added, org. phase sepd., dried, solvent removed; compound wasnot obtained in pure state;

DOI:10.1016/0022-328X(87)85003-9

Reference yield:

(CH3)(C6H5)CC(Sn(CH3)3)2 (103670-46-8) + trimethyllead chloride (1520-78-1) → C6H5(CH3)CC(Sn(CH3)3)Pb(CH3)3 (112166-80-0,112166-81-1) + C6H5(CH3)CC(Sn(CH3)3)Pb(CH3)3 (112166-80-0,112166-81-1)

Guidance literature:

With methyllithium; In 1,2-dimethoxyethane; equimolar mixt. of distannylalkene and MeLi in DME was stirred at -78°C for 1-2 h under Ar, added to 1 equiv of Me3PbCl in DME, stirred for 1 h at -78°C, allowed to warm to room temp.; E/Z ratio 80:20 according to (1)H NMR data; water was added, org. phase sepd., dried, solvent removed; compound wasnot obtained in pure state;

DOI:10.1016/0022-328X(87)85003-9

Reference yield:

C6H5(CH3)CC(Sn(CH3)3)Pb(CH3)3 (112166-81-1) + methyllithium (917-54-4) → C6H5(CH3)CC(Li)Pb(CH3)3 (112167-09-6) + C6H5(CH3)CC(Li)Pb(CH3)3 (112167-10-9)

Guidance literature:

In tetrahydrofuran; byproducts: Me4Sn; an equimolar amount of plumbyl(stannyl)alkene was added to a THF soln. of MeLi at -78°C under Ar, soln. was kept for 1 h; E/Z ratio 77:33 according to (1)H NMR data; soln. was subjected to (1)H NMR analysis at room temp.;

DOI:10.1016/0022-328X(87)85003-9

upstream raw materials:

(CH₃)(C₆H₅)CC(Sn(CH₃)3)2

trimethyllead chloride

Downstream raw materials:

C₆H₅(CH₃)CC(Li)Pb(CH₃)3

C₆H₅(CH₃)CC(Li)Pb(CH₃)3

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