Dimethyl(3-methylbutyl)phenylsilane

Base Information

Chemical Name:Dimethyl(3-methylbutyl)phenylsilane
CAS No.:112197-44-1
Molecular Formula:C13H22Si
Molecular Weight:206.403
Hs Code.:
DSSTox Substance ID:DTXSID90553712
Wikidata:Q82434370

Synonyms:112197-44-1;Dimethyl(3-methylbutyl)phenylsilane;DTXSID90553712

Suppliers and Price of Dimethyl(3-methylbutyl)phenylsilane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Total 0 raw suppliers

Chemical Property of Dimethyl(3-methylbutyl)phenylsilane

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:4
Exact Mass:206.149077236
Heavy Atom Count:14
Complexity:155

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(C)CC[Si](C)(C)C1=CC=CC=C1

Technology Process of Dimethyl(3-methylbutyl)phenylsilane

There total 9 articles about Dimethyl(3-methylbutyl)phenylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: C₈H₁₁LiSi*LiCl

: 107-82-4
i-pentyl bromide

: 112197-44-1
isopentyldimethyl(phenyl)silane

Guidance literature:: C₈H₁₁LiSi*LiCl; With magnesium bromide; In tetrahydrofuran; at 66 ℃; for 0.166667h; Schlenk technique; Inert atmosphere;

i-pentyl bromide; With ferric(III) bromide; N,N,N,N,-tetramethylethylenediamine; In tetrahydrofuran; at 0 ℃; for 1.5h; Schlenk technique; Inert atmosphere;
DOI:10.1002/anie.201807640

Reference yield: 85.0%

: 71864-24-9
(chlorolithiomethyl)dimethylphenylsilane

: 40098-43-9,99591-51-2
diisobutyl[(1E)-oct-1-en-1-yl]aluminum

: 112197-44-1
isopentyldimethyl(phenyl)silane

: 112197-45-2
(E)-(n-Hept)CH=CHSiMe₂Ph

Guidance literature:: With water; In tetrahydrofuran; cyclohexane; addn. of 2.0 mmol of the Al compound to 1.5 equiv. of LiCH(Cl)SiMe2Ph at -78°C, followed by warming the mixt. to 23°C, stirring at this temp. for 1 h, and treatment with water at 0°C; ext.; chromy. (silica gel, pentane); yields detd. by GLC; product distribution depends on reaction temp.;
DOI:10.1021/ja00210a081

Reference yield: 62.0%

: 100-99-2,130565-62-7
triisobutylaluminum

: 71864-24-9
(chlorolithiomethyl)dimethylphenylsilane

: 112197-44-1
isopentyldimethyl(phenyl)silane

Guidance literature:: With water; In tetrahydrofuran; cyclohexane; byproducts: (CH3)3Si(C6H5); addn. of 2.0 mmol i-Bu3Al to 1.5 equiv. of LiCH(Cl)SiMe2Ph at -78°C, followed by warming the mixt. to 23°C, stirring at this temp. for 6 h, and treatment with water at 0°C; extn.; chromy. (silica gel, pentane); Kinetics;
DOI:10.1021/ja00210a081