Technology Process of Dimethyl(3-methylbutyl)phenylsilane
There total 9 articles about Dimethyl(3-methylbutyl)phenylsilane which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
C8H11LiSi*LiCl;
With
magnesium bromide;
In
tetrahydrofuran;
at 66 ℃;
for 0.166667h;
Schlenk technique;
Inert atmosphere;
i-pentyl bromide;
With
ferric(III) bromide; N,N,N,N,-tetramethylethylenediamine;
In
tetrahydrofuran;
at 0 ℃;
for 1.5h;
Schlenk technique;
Inert atmosphere;
DOI:10.1002/anie.201807640
- Guidance literature:
-
With
water;
In
tetrahydrofuran; cyclohexane;
addn. of 2.0 mmol of the Al compound to 1.5 equiv. of LiCH(Cl)SiMe2Ph at -78°C, followed by warming the mixt. to 23°C, stirring at this temp. for 1 h, and treatment with water at 0°C; ext.; chromy. (silica gel, pentane); yields detd. by GLC; product distribution depends on reaction temp.;
DOI:10.1021/ja00210a081
- Guidance literature:
-
With
water;
In
tetrahydrofuran; cyclohexane;
byproducts: (CH3)3Si(C6H5); addn. of 2.0 mmol i-Bu3Al to 1.5 equiv. of LiCH(Cl)SiMe2Ph at -78°C, followed by warming the mixt. to 23°C, stirring at this temp. for 6 h, and treatment with water at 0°C; extn.; chromy. (silica gel, pentane);
Kinetics;
DOI:10.1021/ja00210a081
