Benzene, [[1-(2-butenylidene)heptyl]sulfonyl]-, (E,E)-

Base Information

• Chemical Name: Benzene, [[1-(2-butenylidene)heptyl]sulfonyl]-, (E,E)-
• CAS No.: 112464-03-6
• Molecular Formula: C₁₇H₂₄O₂S
• Molecular Weight: 292.442
• Mol file: 112464-03-6.mol

Synonyms:

Chemical Property of Benzene, [[1-(2-butenylidene)heptyl]sulfonyl]-, (E,E)-

Chemical Property:

Purity/Quality:

99.90% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Benzene, [[1-(2-butenylidene)heptyl]sulfonyl]-, (E,E)-

There total 1 articles about Benzene, [[1-(2-butenylidene)heptyl]sulfonyl]-, (E,E)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 20.0%

bisbenzene (107735-52-4) → EE-<(2-butene 1-ylidene heptyl)sulfonyl>benzene (112464-03-6)

Guidance literature:

With potassium tert-butylate; In diethyl ether; water; for 0.0833333h; Ambient temperature;

DOI:10.1016/S0040-4020(01)90023-7

Reference yield:

EE-<(2-butene 1-ylidene heptyl)sulfonyl>benzene (112464-03-6) → [((E)-Undec-3-ene)-5-sulfonyl]-benzene

Guidance literature:

Multi-step reaction with 2 steps

1: 15 percent / n-butylmagnesium chloride / 2percent Ni(acac)2 / tetrahydrofuran / 1 h / 20 °C

2: 50 percent / sodium dithionite, sodium hydrogen carbonate / Adogen 464 / cyclohexane; H₂O / 18 h / Heating

With sodium dithionite; butyl magnesium bromide; sodium hydrogencarbonate; bis(acetylacetonate)nickel(II); adogen 464; In tetrahydrofuran; cyclohexane; water;

DOI:10.1016/S0040-4020(01)90023-7

upstream raw materials:

bisbenzene

Refernces