2-Pentadecanone,6,10,14-trimethyl-, (6R,10R)-

Base Information

• Chemical Name: 2-Pentadecanone,6,10,14-trimethyl-, (6R,10R)-
• CAS No.: 16825-16-4
• Molecular Formula: C18H36 O
• Molecular Weight: 268.483
• Mol file: 16825-16-4.mol

Synonyms:2-Pentadecanone,6,10,14-trimethyl-, [R-(R*,R*)]-; (+)-Phytone;(6R,10R)-6,10,14-Trimethylpentadecan-2-one; (R,R)-Phytone; Phytol ketone;Phytone; Phytone (ketone)

Chemical Property of 2-Pentadecanone,6,10,14-trimethyl-, (6R,10R)-

Chemical Property:

• Boiling Point: 316.8°Cat760mmHg
• Flash Point: 95°C
• Density: 0.828g/cm³

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2-Pentadecanone,6,10,14-trimethyl-, (6R,10R)-

There total 24 articles about 2-Pentadecanone,6,10,14-trimethyl-, (6R,10R)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(5Z,9Z)-6,10,14-trimethylpentadeca-5,9,13-trien-2-one (3796-69-8) → 6,10,14-Trimethyl-2-pentadecanon (502-69-2) + (6S,10R)-6,10,14-trimethylpentadecan-2-one (13955-75-4) + (6R,10R)-6,10,14-trimethylpentadecan-2-one (16825-16-4)

Guidance literature:

With C₃₇H₄₀IrNOP⁽¹⁺⁾*C₃₂H₁₂BF₂₄^(1-); hydrogen; In 2,2,2-trifluoroethanol; at 20 ℃; for 20h; under 37503.8 Torr; Autoclave; Inert atmosphere;

Reference yield:

6,10,14-trimethyl-5,9,13-pentadecatriene-2-on (1117-52-8) → 6,10,14-Trimethyl-2-pentadecanon (502-69-2) + (6R,10R)-6,10,14-trimethylpentadecan-2-one (16825-16-4)

Guidance literature:

With C₃₂H₁₂BF₂₄^(1-)*C₃₇H₄₂IrNOP⁽¹⁺⁾; hydrogen; In dichloromethane; at 20 ℃; for 14h; under 37503.8 Torr; stereoselective reaction; Autoclave; Inert atmosphere;

Reference yield:

6,10,14-trimethyl-5,9,13-pentadecatriene-2-on (1117-52-8) → (6S,10S)-6,10,14-trimethylpentadecan-2-one (502-69-2,13955-75-4,16825-16-4,22571-87-5,57760-55-1,96093-84-4,125354-91-8)

Guidance literature:

With hydrogen; C₃₂H₁₂BF₂₄^(1-)*C₄₅H₄₄IrNOP⁽¹⁺⁾; In dichloromethane; at 20 ℃; for 14h; under 37503.8 Torr; Product distribution / selectivity; Autoclave;

upstream raw materials:

(R)-6,10,14-trimethylpentadec-5-en-2-one

(3Ξ,7R)-3,7,11-trimethyl-dodecanoic acid

levulinic acid

sodium ethyl acetylacetate enolate

Downstream raw materials:

3,7,11,15-tetramethyl-hexadec-1-yn-3-ol

(6R,10R)-2-Hydroxy-2.6.10.14-tetramethyl-pentadecan

(Z)-phytol

phytol