6,13-Dihydrodibenzo(b,i)phenazine

Base Information

• Chemical Name: 6,13-Dihydrodibenzo(b,i)phenazine
• CAS No.: 10350-06-8
• Molecular Formula: C20H14 N2
• Molecular Weight: 282.345
• Hs Code.: 2933990090
• European Community (EC) Number: 233-763-5
• NSC Number: 155177
• DSSTox Substance ID: DTXSID20145881
• Nikkaji Number: J236.485I
• Wikidata: Q83010565
• Mol file: 10350-06-8.mol

Synonyms:6,13-Dihydrodibenzo(b,i)phenazine;10350-06-8;6,13-dihydrodibenzo[b,i]phenazine;EINECS 233-763-5;Dibenzo(b,i)phenazine, 6,13-dihydro-;Dibenzo[b,i]phenazine, 6,13-dihydro-;2,13-diazapentacyclo[12.8.0.03,12.05,10.016,21]docosa-1(22),3,5,7,9,11,14,16,18,20-decaene;NSC155177;SCHEMBL9921312;DTXSID20145881;c12cc3ccccc3cc1Nc4cc5ccccc5cc4N2;6,13-Diaza-6,13-dihydropentacene;6,13-dihydro-dibenzo[b,i]phenazine;NSC 155177;NSC-155177;6,13-DIHYDRO-6,13-DIAZAPENTACENE

Chemical Property of 6,13-Dihydrodibenzo(b,i)phenazine

Chemical Property:

• Vapor Pressure: 6.71E-12mmHg at 25°C
• Boiling Point: 544.1°Cat760mmHg
• Flash Point: 372.3°C
• PSA: 31.58000
• Density: 1.247g/cm³
• LogP: 5.51780
• XLogP3: 4.8
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 282.115698455
• Heavy Atom Count: 22
• Complexity: 335

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C2C=C3C(=CC2=C1)NC4=CC5=CC=CC=C5C=C4N3

Technology Process of 6,13-Dihydrodibenzo(b,i)phenazine

There total 2 articles about 6,13-Dihydrodibenzo(b,i)phenazine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

→ 6,13-dihydrodibenzophenazine (10350-06-8)

Guidance literature:

With sodium dithionite; In ethanol; water; at 20 ℃; for 4h; Inert atmosphere;

Reference yield: 80.0%

2,3-Diaminonaphthalene (771-97-1) + 2,3-naphthalenediol (92-44-4) → 6,13-dihydrodibenzophenazine (10350-06-8)

Guidance literature:

at 180 ℃; for 1h;

DOI:10.1021/ja036466+

Reference yield: 58.0%

iodobenzene (591-50-4) + 6,13-dihydrodibenzophenazine (10350-06-8) → C32H22N2

Guidance literature:

With tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; potassium tert-butylate; ruphos; In toluene; Reflux;

DOI:10.1002/cplu.201600465

upstream raw materials:

2,3-Diaminonaphthalene

2,3-naphthalenediol

Downstream raw materials:

Dibenzophenazin

6,13-dimethyl-6,13-dihydrodibenzophenazine

Refernces

• 1、 Miao, Qian,Nguyen, Thuc-Quyen,Someya, Takao,Blanchet, Graciela B.,Nuckolls, Colin. "Synthesis, assembly, and thin film transistors of dihydrodiazapentacene: An isostructural motif for pentacene". . p. 10284 - 10287. Retrieved 2003.
• 2、 Manassen,Khalif. "-". . p. 1943. Retrieved 1966.