Ggapga

Base Information

Chemical Name:Ggapga
CAS No.:131088-79-4
Molecular Formula:C₂₇H₄₅N₃O₁₉
Molecular Weight:715.663
Hs Code.:
DSSTox Substance ID:DTXSID90156888
Wikidata:Q83025005
Mol file:131088-79-4.mol

Synonyms:GGAPGA;O-alpha-D-glucopyranosyl-(1-6)-O-beta-D-glucopyranosyl-(1-6)-1-N-(L-aspart-1-oyl-(L-proline)-4-oyl)-alpha-D-glucopyranosylamine;O-glucopyranosyl-(1-6)-O-glucopyranosyl-(1-6)-1-N-(aspart-1-oyl-proline-4-oyl)glucopyranosylamine

Suppliers and Price of Ggapga

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 1 raw suppliers

Chemical Property of Ggapga

Chemical Property:

Vapor Pressure:0mmHg at 25°C
Boiling Point:1138.7°Cat760mmHg
Flash Point:642.5°C
PSA：362.17000
Density:1.73g/cm³
LogP:-7.17760
XLogP3:-8.7
Hydrogen Bond Donor Count:13
Hydrogen Bond Acceptor Count:20
Rotatable Bond Count:13
Exact Mass:715.26472621
Heavy Atom Count:49
Complexity:1140

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1CC(N(C1)C(=O)C(CC(=O)N)NC2C(C(C(C(O2)CO)O)OC3C(C(C(C(O3)CO)O)O)O)OC4C(C(C(C(O4)CO)O)O)O)C(=O)O
Isomeric SMILES:C1C[C@H](N(C1)C(=O)[C@H](CC(=O)N)N[C@@H]2[C@@H]([C@H]([C@@H]([C@H](O2)CO)O)O[C@@H]3[C@@H]([C@H]([C@@H]([C@H](O3)CO)O)O)O)O[C@H]4[C@@H]([C@H]([C@@H]([C@H](O4)CO)O)O)O)C(=O)O

Technology Process of Ggapga

There total 21 articles about Ggapga which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 131110-17-3,131176-94-8,138921-64-9,138921-66-1
O-α-D-glucopyranosyl-(1->6)-O-β-D-glucopyranosyl-(1->6)-2,3-di-O-benzyl-1-N--α-D-glucopyranosylamine

: 131088-79-4,131176-21-1,138921-65-0,138921-67-2
O-α-D-Glucopyranosyl-(1->6)-O-β-D-glucopyranosyl-(1->6)-N--α-D-glucopyranosylamine

Guidance literature:: With hydrogen; palladium on activated charcoal; In ethanol; water; for 24h;
DOI:10.1016/0008-6215(90)80006-O

Reference yield: 82.0%

: 131110-17-3,131176-94-8,138921-64-9,138921-66-1
O-α-D-glucopyranosyl-(1-6)-O-β-D-glucopyranosyl-(1-6)-2,3-di-O-benzyl-1-N--β-D-glucopyranosylamine

: 131088-79-4,131176-21-1,138921-65-0,138921-67-2
O-α-D-glucopyranosyl-(1->6)-O-β-D-glucopyranosyl-(1->6)-1-N--β-D-glucopyranosylamine

Guidance literature:: With hydrogen; palladium on activated charcoal; In ethanol; water; for 24h;
DOI:10.1016/0008-6215(90)80006-O

Reference yield:

: 131088-76-1
N-(tert-butoxycarbonyl)-L-aspartyl-L-proline methyl ester

: 131088-79-4,131176-21-1,138921-65-0,138921-67-2
O-α-D-Glucopyranosyl-(1->6)-O-β-D-glucopyranosyl-(1->6)-N--α-D-glucopyranosylamine

Guidance literature:: Multi-step reaction with 4 steps

1: O,O-diethylcyanophosphate, Et₃N / dimethylformamide / 1) 1 h, 0 deg C, 2) 24 h, r.t.

2: 60.4 percent / 85percent HCO₂H / 5 h / Ambient temperature

3: NaOMe

4: H₂ / 10percent Pd/C / ethanol; H₂O / 24 h

With formic acid; diethyl cyanophosphonate; hydrogen; sodium methylate; triethylamine; palladium on activated charcoal; In ethanol; water; N,N-dimethyl-formamide;
DOI:10.1248/cpb.39.2699