Hexanoic acid, diphenylmethyl ester

Base Information

• Chemical Name: Hexanoic acid, diphenylmethyl ester
• CAS No.: 113548-18-8
• Molecular Formula: C19H22O2
• Molecular Weight: 282.382
• Mol file: 113548-18-8.mol

Synonyms:

Chemical Property of Hexanoic acid, diphenylmethyl ester

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Hexanoic acid, diphenylmethyl ester

There total 1 articles about Hexanoic acid, diphenylmethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

Diphenylmethane (101-81-5) + hexanoic acid (142-62-1) → diphenylmethyl hexanoate (113548-18-8)

Guidance literature:

With 2,3-dicyano-5,6-dichloro-p-benzoquinone; In 1,2-dichloro-ethane; at 100 ℃; for 8h; Inert atmosphere; Sealed tube;

DOI:10.3390/molecules25071527

Reference yield:

diphenylmethyl hexanoate (113548-18-8) → 2-(diphenylmethoxy)-1-heptene (113548-20-2)

Guidance literature:

With pyridine; In tetrahydrofuran; toluene; Yield given; 1.) -40 deg C, 1 h, 2.) RT, 11 h;

DOI:10.1021/jo00244a013

Reference yield:

diphenylmethyl hexanoate (113548-18-8) → 2-(diphenylmethoxy)-1-heptanol (113628-00-5)

Guidance literature:

Multi-step reaction with 2 steps

1: pyridine / toluene; tetrahydrofuran / 1.) -40 deg C, 1 h, 2.) RT, 11 h

2: 1.) (+)-diisopinocampheylborane dimer, 2.) NaOH, H₂O₂ / 1.) THF, RT, 20 h, 2.) THF, RT, 4 h

With pyridine; sodium hydroxide; (+)-diisopinocampheylborane dimer; dihydrogen peroxide; In tetrahydrofuran; toluene;

DOI:10.1021/jo00244a013

upstream raw materials:

Diphenylmethane

hexanoic acid

Downstream raw materials:

2-(diphenylmethoxy)-1-heptene

2-(diphenylmethoxy)-1-heptanol