1-(2-Vinylcyclopropyl)-1-hexene

Base Information

Chemical Name:1-(2-Vinylcyclopropyl)-1-hexene
CAS No.:22822-99-7
Molecular Formula:C₁₁H₁₈
Molecular Weight:150.264
Hs Code.:
Nikkaji Number:J2.365.071A
Mol file:22822-99-7.mol

Synonyms:1-(2-VINYLCYCLOPROPYL)-1-HEXENE;22822-99-7;(.+/-.)-Dictyopterene A;UZAYYMIBUZEMAI-BQYQJAHWSA-N;1-(1-Hexenyl)-2-vinylcyclopropane;1-[(1E)-1-Hexenyl]-2-vinylcyclopropane #;1-Hexene, 1-(2-vinylcyclopropyl)-, (E)-trans-(.+.)-;1-Hexene, 1-(2-vinylcyclopropyl)-, (E)-trans-(.+/-.)-;Cyclopropane, 1-ethenyl-2-hexenyl-, [1.alpha.,2.beta.(E)]-(.+.)-;Cyclopropane, 1-ethenyl-2-hexenyl-, [1.alpha.,2.beta.(E)]-(.+/-.)-

Suppliers and Price of 1-(2-Vinylcyclopropyl)-1-hexene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 1-(2-Vinylcyclopropyl)-1-hexene

Chemical Property:

Vapor Pressure:0.867mmHg at 25°C
Boiling Point:187.5°Cat760mmHg
Flash Point:54.8°C
PSA：0.00000
Density:0.942g/cm³
LogP:3.55490
XLogP3:4.1
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:5
Exact Mass:150.140850574
Heavy Atom Count:11
Complexity:144

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCCCC=CC1CC1C=C
Isomeric SMILES:CCCC/C=C/C1CC1C=C

Technology Process of 1-(2-Vinylcyclopropyl)-1-hexene

There total 48 articles about 1-(2-Vinylcyclopropyl)-1-hexene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 2065-66-9
methyl-triphenylphosphonium iodide

: (1S,2R)-2-(hex-1-enyl)cyclopropanecarbaldehyde

: 22822-99-7,22823-03-6,24519-26-4,25047-20-5,35501-91-8,50265-47-9,50265-49-1,53956-87-9,53956-88-0,53956-89-1,77210-40-3,99438-15-0,99438-16-1,106137-59-1,106137-61-5,133576-11-1
(1S,2R)-1-(hex-1-en-1-yl)-2-vinylcyclopropane

Guidance literature:: methyl-triphenylphosphonium iodide; With n-butyllithium; In tetrahydrofuran; hexane; at -20 ℃; for 0.0833333h;

(1S,2R)-2-(hex-1-enyl)cyclopropanecarbaldehyde; In tetrahydrofuran; hexane; at -78 ℃; for 0.25h;
DOI:10.1246/bcsj.73.409

Reference yield: 84.0%

: C₁₈H₂₆N₂O₂S

: 22822-99-7,22823-03-6,24519-26-4,25047-20-5,35501-91-8,50265-47-9,50265-49-1,53956-87-9,53956-88-0,53956-89-1,77210-40-3,99438-15-0,99438-16-1,106137-59-1,106137-61-5,133576-11-1
1S,2R-Dictyopterene C

Guidance literature:: With lithium diisopropyl amide; In tetrahydrofuran; hexane; for 6h; Ambient temperature;
DOI:10.1016/S0040-4020(01)85604-0

Reference yield:

: 56722-23-7
(5Z)-1,5-undecadien-3-ol

: 22822-99-7,22823-03-6,24519-26-4,25047-20-5,35501-91-8,50265-47-9,50265-49-1,53956-87-9,53956-88-0,53956-89-1,77210-40-3,99438-15-0,99438-16-1,106137-59-1,106137-61-5,133576-11-1
(+/-)-dictyopterene A

Guidance literature:: Multi-step reaction with 7 steps

1: 41 percent / pyridinium chlorochromate / CH₂Cl₂ / 1 h / Ambient temperature

2: 42 percent / toluene / 0.25 h / 0 °C

3: 92 percent / NaBH₄ / methanol / 0.5 h / 0 °C

4: pyridine / 1 h / 0 °C

5: 64 percent / CH₃COOK / acetone; H₂O / 20 h / 80 °C

6: H₃COOCN(-)SO₂N(+)(C₂H₅)3, NaH / 1,2-dimethoxy-ethane / 17 h / 20 - 80 °C

7: 1) CF₃SO₃CH₂COOC₂H₅, 2) DBU / 1) CH₃CN, room temp., 20 h, 2) DMF, 50 deg C, 3 h

With sodium tetrahydroborate; Burgess Reagent; ethoxycarbonylmethyl trifluoromethanesulfonate; potassium acetate; sodium hydride; 1,8-diazabicyclo[5.4.0]undec-7-ene; pyridinium chlorochromate; In pyridine; methanol; 1,2-dimethoxyethane; dichloromethane; water; acetone; toluene;
DOI:10.1016/0040-4039(80)80163-8