mycorrhizin A

Base Information

Chemical Name:mycorrhizin A
CAS No.:64356-85-0
Molecular Formula:C₁₄H₁₅ClO₄
Molecular Weight:282.724
Hs Code.:
Mol file:64356-85-0.mol

Synonyms:1H,7H-Cyclopropa[c]benzofuran-4,7(3aH)-dione,5-(1-chloro-1-propenyl)-1a,2-dihydro-3a-hydroxy-2,2-dimethyl-, [1aR-[1aa,3ab,5(Z),7aS*]]-;1H,7H-Cyclopropa[c]benzofuran-4,7(3aH)-dione,5-[(1Z)-1-chloro-1-propenyl]-1a,2-dihydro-3a-hydroxy-2,2-dimethyl-,(1aR,3aS,7aS)- (9CI); (+)-Mycorrhizin A; Mycorrhizin A

Suppliers and Price of mycorrhizin A

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 2 raw suppliers

Chemical Property of mycorrhizin A

Chemical Property:

Vapor Pressure:1.23E-08mmHg at 25°C
Boiling Point:415.4°Cat760mmHg
Flash Point:205°C
PSA：63.60000
Density:1.4g/cm³
LogP:1.71090

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of mycorrhizin A

There total 6 articles about mycorrhizin A which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

: 64356-86-1,81445-42-3
(1aS,3aR,7aR)-5-((Z)-1-Chloro-propenyl)-3a-methoxy-2,2-dimethyl-1a,2-dihydro-1H-3-oxa-cyclopropa[c]indene-4,7-dione

: 64356-85-0,75715-04-7,81445-41-2
(+/-)-mycorrhizin A

Guidance literature:: With tetrafluoroboric acid; In 1,4-dioxane; at 80 ℃; for 0.25h;
DOI:10.1021/ja00373a065

Reference yield:

: 81407-89-8
(1aS,3aR,5R,7aR)-3a-Methoxy-2,2-dimethyl-5-((E)-1-trimethylsilanyl-propenyl)-tetrahydro-3-oxa-cyclopropa[c]indene-4,7-dione

: 64356-85-0,75715-04-7,81445-41-2
(+/-)-mycorrhizin A

Guidance literature:: Multi-step reaction with 2 steps

1: SeO₂ / pyridine; 2-methyl-propan-2-ol / 5 h / Heating

2: 1.) Cl₂, 2.) KF / 1.) -75 deg C, 2.) Me₂SO, 25 deg C

With potassium fluoride; selenium(IV) oxide; chlorine; In pyridine; tert-butyl alcohol;
DOI:10.1021/ja00373a065

Reference yield:

: 81407-88-7,81495-65-0
(1aS,3aR,4S,5R,7aR)-4-Hydroxy-3a-methoxy-2,2-dimethyl-5-((E)-1-trimethylsilanyl-propenyl)-hexahydro-3-oxa-cyclopropa[c]inden-7-one

: 64356-85-0,75715-04-7,81445-41-2
(+/-)-mycorrhizin A

Guidance literature:: Multi-step reaction with 3 steps

1: 65 percent / (COCl)2, Et₃N / dimethylsulfoxide

2: SeO₂ / pyridine; 2-methyl-propan-2-ol / 5 h / Heating

3: 1.) Cl₂, 2.) KF / 1.) -75 deg C, 2.) Me₂SO, 25 deg C

With potassium fluoride; selenium(IV) oxide; oxalyl dichloride; chlorine; triethylamine; In pyridine; dimethyl sulfoxide; tert-butyl alcohol;
DOI:10.1021/ja00373a065