3-(4-Bromophenyl)glutaric anhydride

Base Information

Chemical Name:3-(4-Bromophenyl)glutaric anhydride
CAS No.:1137-61-7
Molecular Formula:C11H9BrO3
Molecular Weight:269.095
Hs Code.:
DSSTox Substance ID:DTXSID40467532
Nikkaji Number:J2.107.818B
Wikidata:Q82294509
Mol file:1137-61-7.mol

Synonyms:1137-61-7;4-(4-bromophenyl)oxane-2,6-dione;3-(4-bromophenyl)glutaric anhydride;2H-Pyran-2,6(3H)-dione, 4-(4-bromophenyl)dihydro-;SCHEMBL657720;4-(4-bromophenyl)dihydro-2H-pyran-2,6(3H)-dione;DTXSID40467532;UVZKTNHKBFICNI-UHFFFAOYSA-N;3-(4-bromophenyl)-glutaric anhydride;AKOS022368796;CS-0241753;EN300-237496;F2189-0932

Suppliers and Price of 3-(4-Bromophenyl)glutaric anhydride

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 3 raw suppliers

Chemical Property of 3-(4-Bromophenyl)glutaric anhydride

Chemical Property:

XLogP3:2
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:1
Exact Mass:267.97351
Heavy Atom Count:15
Complexity:253

Purity/Quality:: 99.90% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1C(CC(=O)OC1=O)C2=CC=C(C=C2)Br

Technology Process of 3-(4-Bromophenyl)glutaric anhydride

There total 6 articles about 3-(4-Bromophenyl)glutaric anhydride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 1141-24-8
3-(4-bromophenyl)pentanedioic acid

: 1137-61-7
3-(4-bromo)-phenylglutaric acid anhydride

Guidance literature:: With acetic anhydride; at 130 ℃;
DOI:10.1021/jm0004953

Reference yield: 61.0%

: 463-51-4
Ketene

: 1122-91-4
4-bromo-benzaldehyde

: 1137-61-7
3-(4-bromo)-phenylglutaric acid anhydride

Guidance literature:: With boron trifluoride diethyl etherate; In dichloromethane; at -40 - 20 ℃; for 4.75h;
DOI:10.1016/j.tetlet.2009.02.193

Reference yield:

: 1122-91-4
4-bromo-benzaldehyde

: 1137-61-7
3-(4-bromo)-phenylglutaric acid anhydride

Guidance literature:: Multi-step reaction with 3 steps

1: piperidine / 20 °C

2: KOH / H₂O / 3 h / 80 °C

3: 83 percent / Ac₂O / 130 °C

With piperidine; potassium hydroxide; acetic anhydride; In water;
DOI:10.1021/jm0004953