(2-Ethyl-3-propyloxiran-2-yl)methanol

Base Information

Chemical Name:(2-Ethyl-3-propyloxiran-2-yl)methanol
CAS No.:78-72-8
Molecular Formula:C₈H₁₆O₂
Molecular Weight:144.214
Hs Code.:
DSSTox Substance ID:DTXSID50999258
Nikkaji Number:J49.423B
Mol file:78-72-8.mol

Synonyms:2,3-Epoxy-2-ethyl hexanol;78-72-8;1-Hexanol, 2,3-epoxy-2-ethyl-;(2-ethyl-3-propyloxiran-2-yl)methanol;SCHEMBL8710726;2,3-epoxy-2-ethyl-1-hexanol;DTXSID50999258;2-Ethyl-3-propyloxirane-2-methanol;LS-75422

Suppliers and Price of (2-Ethyl-3-propyloxiran-2-yl)methanol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 5 raw suppliers

Chemical Property of (2-Ethyl-3-propyloxiran-2-yl)methanol

Chemical Property:

Vapor Pressure:0.0601mmHg at 25°C
Boiling Point:205.3°Cat760mmHg
Flash Point:73.9°C
PSA：32.76000
Density:0.942g/cm³
LogP:1.32640
XLogP3:1.3
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:4
Exact Mass:144.115029749
Heavy Atom Count:10
Complexity:114

Purity/Quality:: 98%min ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCCC1C(O1)(CC)CO

Technology Process of (2-Ethyl-3-propyloxiran-2-yl)methanol

There total 4 articles about (2-Ethyl-3-propyloxiran-2-yl)methanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1235457-83-6
(2R,3S)-2-ethyl-3-propyloxirane-2-carbaldehyde

: 1235457-92-7,78-72-8
((2S,3S)-2-ethyl-3-propyloxiran-2-yl)methanol

Guidance literature:: With sodium tetrahydroborate; In ethanol; at 20 ℃; for 0.166667h;
DOI:10.1021/ja402058v

Reference yield:

: 64344-45-2
(E)-2-ethyl-2-hexenal

: 1235457-92-7,78-72-8
((2S,3S)-2-ethyl-3-propyloxiran-2-yl)methanol

Guidance literature:: Multi-step reaction with 2 steps

1: 9-epi-9-amino-9-deoxyquinine; dihydrogen peroxide; (R_a)-4-hydroxy-2,6-diphenyldinaphtho[1,3,2]dioxaphosphepine 4-oxide / tetrahydrofuran; water / 24 h / 20 - 50 °C

2: sodium tetrahydroborate / ethanol / 0.17 h / 20 °C

With 9-epi-9-amino-9-deoxyquinine; (R_a)-4-hydroxy-2,6-diphenyldinaphtho[1,3,2]dioxaphosphepine 4-oxide; sodium tetrahydroborate; dihydrogen peroxide; In tetrahydrofuran; ethanol; water;
DOI:10.1021/ja402058v

Reference yield:

: 90112-78-0
2-ethyl-3-propyloxirane-2-carbaldehyde

: 1235457-92-7,78-72-8
((2S,3S)-2-ethyl-3-propyloxiran-2-yl)methanol

: 78-72-8
(2-ethyl-3-propyloxiran-2-yl)methanol

Guidance literature:: With sodium tetrahydroborate; for 0.166667h; optical yield given as %ee; enantioselective reaction;
DOI:10.1021/ja1037935