Uranium, tris[2,6-bis(1,1-dimethylethyl)phenolato](tetrahydrofuran)-

Base Information

• Chemical Name: Uranium, tris[2,6-bis(1,1-dimethylethyl)phenolato](tetrahydrofuran)-
• CAS No.: 116184-73-7
• Molecular Formula: C46H71O4U
• Molecular Weight: 926.096
• Mol file: 116184-73-7.mol

Synonyms:

Chemical Property of Uranium, tris[2,6-bis(1,1-dimethylethyl)phenolato](tetrahydrofuran)-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Uranium, tris[2,6-bis(1,1-dimethylethyl)phenolato](tetrahydrofuran)-

There total 4 articles about Uranium, tris[2,6-bis(1,1-dimethylethyl)phenolato](tetrahydrofuran)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

tetrahydrofuran (109-99-9,24979-97-3,77392-70-2) + UI3(1,4-dioxane)1.5 + potassium 2,6-di-tert-butylphenolate (24676-69-5) → (THF)U(O-2,6-(Bu-t)2C6H3)3 (116184-73-7)

Guidance literature:

at 20 ℃; for 1h;

Reference yield: 81.0%

UI3(1,4-dioxane)1.5 + potassium 2,6-di-tert-butylphenolate (24676-69-5) → (THF)U(O-2,6-(Bu-t)2C6H3)3 (116184-73-7)

Guidance literature:

In tetrahydrofuran; (N2); charging of scintillation vial with stir bar, UI3(1,4-dioxane)1.5 and THF, addn. of THF soln. of K(O-2,6-t-Bu2C6H3), stirring for 1 h at room temp.; removal of volatiles under reduced pressure, extn. into pentane, filtration, removal of volatiles under reduced pressure;

DOI:10.1021/om200093q

Reference yield:

2,6-di-tert-butylphenol (128-39-2) → (THF)U(O-2,6-(Bu-t)2C6H3)3 (116184-73-7)

Guidance literature:

Multi-step reaction with 2 steps

1: hexane

2: tetrahydrofuran

In tetrahydrofuran; hexane;

DOI:10.1021/ja00225a067

upstream raw materials:

tetrahydrofuran

2,6-di-tert-butylphenol

potassium 2,6-di-tert-butylphenolate