tert-Butyl{[9-methoxy-9-(phenylsulfanyl)nonyl]oxy}dimethylsilane

Base Information

Chemical Name:tert-Butyl{[9-methoxy-9-(phenylsulfanyl)nonyl]oxy}dimethylsilane
CAS No.:116204-89-8
Molecular Formula:C22H40O2SSi
Molecular Weight:396.71
Hs Code.:
DSSTox Substance ID:DTXSID00554114
Mol file:116204-89-8.mol

Synonyms:116204-89-8;DTXSID00554114;tert-Butyl{[9-methoxy-9-(phenylsulfanyl)nonyl]oxy}dimethylsilane

Suppliers and Price of tert-Butyl{[9-methoxy-9-(phenylsulfanyl)nonyl]oxy}dimethylsilane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 1 raw suppliers

Chemical Property of tert-Butyl{[9-methoxy-9-(phenylsulfanyl)nonyl]oxy}dimethylsilane

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:14
Exact Mass:396.25182822
Heavy Atom Count:26
Complexity:349

Purity/Quality:: 99.90% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(C)(C)[Si](C)(C)OCCCCCCCCC(OC)SC1=CC=CC=C1

Technology Process of tert-Butyl{[9-methoxy-9-(phenylsulfanyl)nonyl]oxy}dimethylsilane

There total 1 articles about tert-Butyl{[9-methoxy-9-(phenylsulfanyl)nonyl]oxy}dimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 13865-50-4
methoxymethyl phenyl sulfide

: 116204-89-8
tert-Butyl-(9-methoxy-9-phenylsulfanyl-nonyloxy)-dimethyl-silane

Guidance literature:: With N,N,N,N,N,N-hexamethylphosphoric triamide; n-butyllithium; In tetrahydrofuran; at -78 - -15 ℃; for 3h;
DOI:10.1016/S0040-4039(01)91357-7

Reference yield: 74.0%

: 24850-33-7
allyltributylstanane

: 116204-89-8
tert-Butyl-(9-methoxy-9-phenylsulfanyl-nonyloxy)-dimethyl-silane

: 116204-97-8
tert-Butyl-(9-methoxy-dodec-11-enyloxy)-dimethyl-silane

: 116204-98-9
tert-Butyl-dimethyl-(9-phenylsulfanyl-dodec-11-enyloxy)-silane

Guidance literature:: With boron trifluoride diethyl etherate; In dichloromethane; at -20 ℃; for 2h; Yields of byproduct given;
DOI:10.1016/S0040-4039(01)91357-7

Reference yield:

: 116204-89-8
tert-Butyl-(9-methoxy-9-phenylsulfanyl-nonyloxy)-dimethyl-silane

: 50767-78-7
(E)-9,11-dodecadien-1-yl acetate

Guidance literature:: Multi-step reaction with 4 steps

1: (2. eq.) BF₃OEt₂ / CH₂Cl₂ / 2 h / -20 °C

2: 1.) mCPBA; 2.) CaCO₃ / 1.) CH₂Cl₂, -50 deg C, 3 h; 2.) toluene, reflux, 12 h

3: Bu₄NF / tetrahydrofuran / 3 h / 15 °C

4: Py / 12 h / 15 °C

With pyridine; boron trifluoride diethyl etherate; tetrabutyl ammonium fluoride; 3-chloro-benzenecarboperoxoic acid; calcium carbonate; In tetrahydrofuran; dichloromethane;
DOI:10.1016/S0040-4039(01)91357-7