10-Undecenoyl chloride

Base Information

• Chemical Name: 10-Undecenoyl chloride
• CAS No.: 38460-95-6
• Molecular Formula: C11H19 Cl O
• Molecular Weight: 202.724
• Hs Code.: 29161910
• European Community (EC) Number: 253-951-0,922-786-2
• NSC Number: 155178
• UNII: 66H2RF37V6
• DSSTox Substance ID: DTXSID5068106
• Nikkaji Number: J54.230J
• Wikidata: Q72515858
• Mol file: 38460-95-6.mol

Synonyms:10-UNDECENOYL CHLORIDE;38460-95-6;undec-10-enoyl chloride;10-undecenoylchloride;10-Undecylenoyl chloride;omega-Undecylenic acid chloride;Undecylenoyl chloride;EINECS 253-951-0;NSC 155178;C11H19ClO;BRN 1635112;.omega.-Undecylenic acid chloride;66H2RF37V6;NSC-155178;EC 253-951-0;4-02-00-01615 (Beilstein Handbook Reference);C11-H19-Cl-O;10-Hendecenoyl Chloride;10-undecenoic acid chloride;SCHEMBL455091;UNII-66H2RF37V6;10-Undecenoyl chloride, 97%;10-UNDECENOYL CHLORIDE,;DTXSID5068106;MFCD00000772;NSC155178;AKOS000121291;LS-158489;FT-0607202;U0008;EN300-20667;A824160

Chemical Property of 10-Undecenoyl chloride

Chemical Property:

• Refractive Index: n20/D 1.454(lit.)
• Boiling Point: 252.2°Cat760mmHg
• Flash Point: 93.3°C
• Density: 0.948g/cm³
• Storage Temp.: Store below +30°C.
• XLogP3: 4.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 9
• Exact Mass: 202.1124429
• Heavy Atom Count: 13
• Complexity: 143

Purity/Quality:

99.9% ^*data from raw suppliers

10-Undecenoyl Chloride >98.0%(T) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): C
• Hazard Codes: C
• Statements: 34-37
• Safety Statements: 26-36/37/39-45

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C=CCCCCCCCCC(=O)Cl
• Uses: 10-Undecenoyl chloride was used as acylating reagent in the synthesis of cellulose ω-carboxyalkanoates and poly(ethylene glycol)–lipid amphiphiles. It was used in synthesis and modification of hyperbranched poly(glycidol).

Technology Process of 10-Undecenoyl chloride

There total 4 articles about 10-Undecenoyl chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

10-undecenoic acid (112-38-9) → undec-10-enoyl chloride (38460-95-6)

Guidance literature:

With thionyl chloride;

DOI:10.1134/S107042801904016X

Reference yield: 59.25%

→ undec-10-enoyl chloride (38460-95-6)

Guidance literature:

Reference yield:

10,11-dibromoundecanoyl chloride (39243-54-4) → undec-10-enoyl chloride (38460-95-6) + undec-9-enoyl chloride (202737-61-9)

Guidance literature:

With 1,2-bis(diphenylphosphino)ethane nickel(II) chloride; tri-n-butyl-tin hydride; In tetrahydrofuran; for 0.5h; Yield given. Yields of byproduct given; Ambient temperature;

DOI:10.1016/S0040-4020(97)10203-4

upstream raw materials:

10-undecenoic acid

10,11-dibromoundecanoyl chloride

Downstream raw materials:

1-(pyrrolidin-1-yl)undec-10-en-1-one

1-(morpholin-4-yl)undec-10-en-1-one

N-thiazol-2-yl-undec-10-enamide

N-pyrimidin-2-yl-undec-10-enamide

Refernces

• 1、 Tueruen, Oguz,Meier, Michael A. R.. "Thiol-ene vs. ADMET: A complementary approach to fatty acid-based biodegradable polymers". . p. 314 - 320. Retrieved 2011.
• 2、 Goethals, Fabienne,Martens, Steven,Espeel, Pieter,Van Den Berg, Otto,Du Prez, Filip E.. "Diversely substituted polyamide structures through thiol-ene polymerization of renewable thiolactone building blocks". . p. 61 - 69. Retrieved 2014.
• 3、 Voges, Andrea B.,Al-Abadleh, Hind A.,Musorrafiti, Michael J.,Bertin, Paul A.,Nguyen, SonBinh T.,Geiger, Franz M.. "Carboxylic acid- and ester-functionalized siloxane scaffolds on glass studied by broadband sum frequency generation". . p. 18675 - 18682. Retrieved 2004.
• 4、 Al-Abadleh, Hind A.,Voges, Andrea B.,Bertin, Paul A.,Nguyen, SonBinh T.,Geiger, Franz M.. "Chromium(VI) binding to functionalized silica/water interfaces studied by nonlinear optical spectroscopy". . p. 11126 - 11127. Retrieved 2004.
• 5、 Peters, Carsten,Billich, Andreas,Ghobrial, Michael,Hoegenauer, Klemens,Ullrich, Thomas,Nussbaumer, Peter. "Synthesis of borondipyrromethene (BODIPY)-labeled sphingosine derivatives by cross-metathesis reaction". . p. 1842 - 1845. Retrieved 2007.
• 6、 -. "Full-spectrum selective reflection annular side chain liquid crystal oligomer film and preparation method thereof". Paragraph 0116; 0121-0123. . Retrieved 2021/08/06.
• 7、 Venkatesh, Yarra,Chaudhuri, Amrita,Mondal, Saugat,Shah, Sk. Sheriff,Singh, N. D. Pradeep. "Wavelength-Orthogonal Photocleavable Monochromophoric Linker for Sequential Release of Two Different Substrates". . p. 295 - 299. Retrieved 2020/01/02.