(4-Bromo-benzylidene)-naphthalen-1-YL-amine

Base Information

• Chemical Name: (4-Bromo-benzylidene)-naphthalen-1-YL-amine
• CAS No.: 116401-74-2
• Molecular Formula: C17H12BrN
• Molecular Weight: 310.193
• European Community (EC) Number: 651-317-1
• Nikkaji Number: J2.228.228J
• Mol file: 116401-74-2.mol

Synonyms:N-(4-Bromobenzylidene)naphthalen-1-amine;(4-BROMO-BENZYLIDENE)-NAPHTHALEN-1-YL-AMINE;STK390978;AKOS003609563;NCGC00342034-01;116401-74-2;AB01334008-02;N-[(E)-(4-bromophenyl)methylidene]naphthalen-1-amine;(E)-1-(4-bromophenyl)-N-(naphthalen-1-yl)methanimine

Chemical Property of (4-Bromo-benzylidene)-naphthalen-1-YL-amine

Chemical Property:

• XLogP3: 4.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 2
• Exact Mass: 309.01531
• Heavy Atom Count: 19
• Complexity: 306

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C1=CC=C2C(=C1)C=CC=C2N=CC3=CC=C(C=C3)Br

Technology Process of (4-Bromo-benzylidene)-naphthalen-1-YL-amine

There total 1 articles about (4-Bromo-benzylidene)-naphthalen-1-YL-amine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

1-amino-naphthalene (134-32-7) + 4-bromo-benzaldehyde (1122-91-4) → [1-(4-Bromo-phenyl)-meth-(E)-ylidene]-naphthalen-1-yl-amine (116401-74-2)

Guidance literature:

for 2h; Ambient temperature;

Reference yield: 91.0%

dimedone (126-81-8) + [1-(4-Bromo-phenyl)-meth-(E)-ylidene]-naphthalen-1-yl-amine (116401-74-2) → 7-(4-bromophenyl)-10,10-dimethyl-7,10,11,12-tetrahydrobenzo[c]acridin-8(9H)-one (117358-62-0)

Guidance literature:

N-benzyl-N,N,N-triethylammonium chloride; In water; at 100 ℃; for 12h;

DOI:10.1016/j.tetlet.2005.08.091

Reference yield: 89.0%

indole (120-72-9) + [1-(4-Bromo-phenyl)-meth-(E)-ylidene]-naphthalen-1-yl-amine (116401-74-2) → 6-(4-bromophenyl)-11H-benzo[h]indolo[3,2-c]quinoline (1429117-83-8)

Guidance literature:

indole; [1-(4-Bromo-phenyl)-meth-(E)-ylidene]-naphthalen-1-yl-amine; With iodine; In N,N-dimethyl acetamide; at 80 ℃; for 18h;

With 2,3-dicyano-5,6-dichloro-p-benzoquinone; In N,N-dimethyl acetamide; at 80 ℃;

DOI:10.1002/cjoc.201200993

upstream raw materials:

1-amino-naphthalene

4-bromo-benzaldehyde

Downstream raw materials:

7-(4-bromophenyl)-10,10-dimethyl-7,10,11,12-tetrahydrobenzo[c]acridin-8(9H)-one

6-(4-bromophenyl)-11H-benzo[h]indolo[3,2-c]quinoline