3,6-Dioxabicyclo[3.1.0]hexane, 1-methyl-2-methylene-

Base Information

Chemical Name:3,6-Dioxabicyclo[3.1.0]hexane, 1-methyl-2-methylene-
CAS No.:116414-65-4
Molecular Formula:C6H8O2
Molecular Weight:112.12700
Hs Code.:
DSSTox Substance ID:DTXSID40473355
Nikkaji Number:J1.281.410K
Mol file:116414-65-4.mol

Synonyms:116414-65-4;1-methyl-2-methylidene-3,6-dioxabicyclo[3.1.0]hexane;3,6-Dioxabicyclo[3.1.0]hexane, 1-methyl-2-methylene- (9CI);3,6-Dioxabicyclo[3.1.0]hexane, 1-methyl-2-methylene-;DTXSID40473355

Suppliers and Price of 3,6-Dioxabicyclo[3.1.0]hexane, 1-methyl-2-methylene-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 2 raw suppliers

Chemical Property of 3,6-Dioxabicyclo[3.1.0]hexane, 1-methyl-2-methylene-

Chemical Property:

PSA：21.76000
LogP:0.68780
XLogP3:0.3
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:0
Exact Mass:112.052429494
Heavy Atom Count:8
Complexity:153

Purity/Quality:: 99.90% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC12C(O1)COC2=C

Technology Process of 3,6-Dioxabicyclo[3.1.0]hexane, 1-methyl-2-methylene-

There total 3 articles about 3,6-Dioxabicyclo[3.1.0]hexane, 1-methyl-2-methylene- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: cis-2,3-epoxy-3-methylpent-4-ynol

: 116414-65-4
3,4-epoxy-3-methyl-2-methyleneoxolane

Guidance literature:: With silver carbonate; In benzene; at 80 ℃; for 1h;

Reference yield: 99.0%

: 176300-50-8
(2R*,3R*)-2,3-epoxy-3-methyl-4-pentyn-1-ol

: 116414-65-4
3,4-epoxy-3-methyl-2-methyleneoxolane

Guidance literature:: With silver carbonate; In benzene; at 80 ℃; for 2h;

Reference yield:

: 6153-05-5,105-29-3
(Z)-3-methylpent-2-en-4-ynol

: 116414-65-4
3,4-epoxy-3-methyl-2-methyleneoxolane

Guidance literature:: Multi-step reaction with 2 steps

1: m-CPBA; sodium bicarbonate / CH₂Cl₂

2: 99 percent / silver carbonate / benzene / 1 h / 80 °C

With sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid; silver carbonate; In dichloromethane; benzene; 1: Epoxidation / 2: Cyclization;