11-Dodecenoic acid, 12-(triphenylgermyl)-, ethyl ester, (Z)-

Base Information

• Chemical Name: 11-Dodecenoic acid, 12-(triphenylgermyl)-, ethyl ester, (Z)-
• CAS No.: 116487-95-7
• Molecular Formula: C₃₂H₄₀GeO₂
• Molecular Weight: 529.258
• Mol file: 116487-95-7.mol

Synonyms:

Chemical Property of 11-Dodecenoic acid, 12-(triphenylgermyl)-, ethyl ester, (Z)-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 11-Dodecenoic acid, 12-(triphenylgermyl)-, ethyl ester, (Z)-

There total 1 articles about 11-Dodecenoic acid, 12-(triphenylgermyl)-, ethyl ester, (Z)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

triphenylgermane (2816-43-5) + 11-dodecynoic acid ethyl ester (108545-41-1) → (Z)-ethyl 11-triphenylgermyl-10-undecenoate (116487-95-7)

Guidance literature:

triethyl borane; In hexane; toluene; addn. of Et3B in hexane to a soln. of acetylene-compd. and Ph3GeH in toluene under Ar, stirring for 12 h at -78°C; purifn. by column chromy. or preparative thin-layer chromy. on silica gel,; elem. anal.; isomer ratio Z/E=>10/1 (detd. by GC, NMR);

DOI:10.1246/bcsj.63.2268

upstream raw materials:

triphenylgermane

11-dodecynoic acid ethyl ester