2,6-Bis(trimethylsilyl)benzenethiol

Base Information

Chemical Name:2,6-Bis(trimethylsilyl)benzenethiol
CAS No.:117526-63-3
Molecular Formula:C12H22SSi2
Molecular Weight:254.544
Hs Code.:
DSSTox Substance ID:DTXSID50572166
Nikkaji Number:J1.012.833A
Wikidata:Q82460443

Synonyms:2,6-Bis(trimethylsilyl)benzenethiol;117526-63-3;DTXSID50572166;2,6-Bis(trimethylsilyl)benzene-1-thiol

Suppliers and Price of 2,6-Bis(trimethylsilyl)benzenethiol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 1 raw suppliers

Chemical Property of 2,6-Bis(trimethylsilyl)benzenethiol

Chemical Property:

Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:2
Exact Mass:254.09807494
Heavy Atom Count:15
Complexity:193

Purity/Quality:: 99.90% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:C[Si](C)(C)C1=C(C(=CC=C1)[Si](C)(C)C)S

Technology Process of 2,6-Bis(trimethylsilyl)benzenethiol

There total 3 articles about 2,6-Bis(trimethylsilyl)benzenethiol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 108-98-5
thiophenol

: 117526-63-3
2,6-bis(trimethylsilyl)benzenethiol

Guidance literature:: Multi-step reaction with 4 steps

1: 92 percent / pyridinium p-toluenesulfonate / CH₂Cl₂ / 4 h / 25 °C

2: 1.) t-BuLi / 1.) THF, HMPA, -95 deg C, 2 h, 2.) 25 deg C

3: 1.) K₂CO₃, aq. AgNO₃, 2.) H₂S / 1.) MeOH, 3 h, 2.) CH₂Cl₂, 1.5 h

With hydrogen sulfide; tert.-butyl lithium; pyridinium p-toluenesulfonate; potassium carbonate; silver nitrate; In dichloromethane;
DOI:10.1021/ja00184a039

Reference yield:

: 20965-36-0
2-(phenylthio)tetrahydro-2H-pyran

: 117526-63-3
2,6-bis(trimethylsilyl)benzenethiol

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) t-BuLi / 1.) THF, HMPA, -95 deg C, 2 h, 2.) 25 deg C

2: 1.) K₂CO₃, aq. AgNO₃, 2.) H₂S / 1.) MeOH, 3 h, 2.) CH₂Cl₂, 1.5 h

With hydrogen sulfide; tert.-butyl lithium; potassium carbonate; silver nitrate;
DOI:10.1021/ja00184a039

Reference yield:

: 117526-61-1
2-(trimethylsilyl)phenyl-2-tetrahydropyranyl sulfide

: 117526-63-3
2,6-bis(trimethylsilyl)benzenethiol

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) K₂CO₃, aq. AgNO₃, 2.) H₂S / 1.) MeOH, 3 h, 2.) CH₂Cl₂, 1.5 h

With hydrogen sulfide; potassium carbonate; silver nitrate;
DOI:10.1021/ja00184a039