3-NITROPHENYLPHENYLSULFIDE

Base Information

• Chemical Name: 3-NITROPHENYLPHENYLSULFIDE
• CAS No.: 37984-02-4
• Molecular Formula: C12H9 N O2 S
• Molecular Weight: 231.275
• Hs Code.: 2930909090
• Mol file: 37984-02-4.mol

Synonyms:Sulfide,m-nitrophenyl phenyl (6CI,7CI); 1-Nitro-3-(phenylthio)benzene; 3-Nitrodiphenylsulfide; 3-Nitrophenyl phenyl sulfide; Phenyl m-nitrophenyl sulfide;m-Nitrophenyl phenyl sulfide

Chemical Property of 3-NITROPHENYLPHENYLSULFIDE

Chemical Property:

• Vapor Pressure: 1.82E-05mmHg at 25°C
• Boiling Point: 374.2°Cat760mmHg
• Flash Point: 180.1°C
• PSA: 71.12000
• Density: 1.31g/cm³
• LogP: 4.26920

Purity/Quality:

99%min ^*data from raw suppliers

1-Nitro-3-(phenylsulfanyl)benzene ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 3-NITROPHENYLPHENYLSULFIDE

There total 21 articles about 3-NITROPHENYLPHENYLSULFIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

m-iodonitrobenzene (645-00-1) + thiophenol (108-98-5) → 3-nitrophenyl phenyl sulfide (37984-02-4)

Guidance literature:

With nanoferrite-dopamine copper catalyst; In isopropyl alcohol; at 120 ℃; for 0.416667h; under 517.162 - 3102.97 Torr; Microwave irradiation;

DOI:10.1039/c2cc17283f

Reference yield: 98.0%

meta-dinitrobenzene (99-65-0) + thiophenol (108-98-5) → 3-nitrophenyl phenyl sulfide (37984-02-4)

Guidance literature:

With potassium carbonate; In N,N-dimethyl-formamide; at 90 - 95 ℃; for 7h;

Reference yield: 97.0%

3-fluoro-1-nitrobenzene (402-67-5) + thiophenol (108-98-5) → 3-nitrophenyl phenyl sulfide (37984-02-4)

Guidance literature:

With potassium carbonate; In N,N-dimethyl-formamide; at 90 - 92 ℃; for 7h;

upstream raw materials:

m-Nitrobenzoldiazophenylsulfid

tetra-n-butylammonium cyanide

sodium thiophenolate

3-nitrophenyldiazonium tetrafluoroborate

Downstream raw materials:

3-nitro-(phenylsulfonyl)benzene

(3-nitro-phenyl)-phenyl sulfoxide

3-phenylthioaniline

3-Phenylsulfinyl-trifluormethansulfonanilid

Refernces

• 1、 Bhattacharjee, Subham,Biswas, Biplab,Choudhury, Prasun,Ghosh, Angshuman,Kumar Dubey, Soumen,Rizzoli, Corrado,Saha, Rajat. "A water soluble Ni-Schiff base complex for homogeneous green catalytic C[sbnd]S cross-coupling reactions". . . Retrieved 2021/12/24.
• 2、 Mohammadinezhad, Arezou,Akhlaghinia, Batool. "CoII immobilized on an aminated magnetic metal-organic framework catalyzed C-N and C-S bond forming reactions: A journey for the mild and efficient synthesis of arylamines and arylsulfides". supporting information. p. 15525 - 15538. Retrieved 2019/10/19.