Technology Process of Gold, bromo(5-phenyl-5H-benzo[b]phosphindole)-
There total 1 articles about Gold, bromo(5-phenyl-5H-benzo[b]phosphindole)- which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
NaBr;
In
ethanol; chloroform; water;
addn. of a saturated 1:1 EtOH/H2O soln. of NaBr to soln. of Au-compd. in CHCl3, stirred magnetically for 1h at ambient temp.; solvent removed (rotary evaporator, 50°C), extd. six times (CH2Cl2), extracts combined, filtered (anhydrous K2CO3 layer), volume reduced, addn. of hexane, placed in a freezer at -20°C, filtered, washed (n-hexane), vac.-dried; elem. anal.;
- Guidance literature:
-
With
Br2;
In
chloroform;
(N2); react. soln. was stirred at ambient temp. for 3 h; filtered; volume reduced; addn. of anhyd. diethyl ether; cooled to 0°C (pptn.); filtered, washed with anhyd. diethyl ether; dried in vac.; elem. anal.;
DOI:10.1016/S0277-5387(00)86058-1
- Guidance literature:
-
In
chloroform-d1;
react. of equimolar mixt. under N2 at 30°C and at -13°C; not isolated, 31P-NMR;
DOI:10.1016/S0277-5387(00)86058-1
