Technology Process of Gold, chloro(3,4-dimethyl-1-phenyl-1H-phosphole)-
There total 1 articles about Gold, chloro(3,4-dimethyl-1-phenyl-1H-phosphole)- which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
In
dichloromethane;
at 22 ℃;
for 3h;
Inert atmosphere;
Schlenk technique;
DOI:10.1021/om301244m
- Guidance literature:
-
With
KPF6;
In
dichloromethane; water;
saturated aq. soln. of KPF6 added to soln. of ligand and complex in CH2Cl2, stirred magnetically at ambient temp. for 1h; solvent removed, extd. (CH2Cl2), extracts combined, wshed with water, dried (anhydrous K2CO3), volume reduced, dropwise addn. of ether, mixt. placed in a freezer at -20°C, filtered, washed (ether), vac.-dried; elem. anal.;
- Guidance literature:
-
With
Cl2;
In
chloroform;
(N2); Cl2 gas was bubbled through the soln. with stirring; filtered; volume reduced; addn. of n-hexane; cooled to 0°C (pptn.); filtered; washed (anhyd. diethyl ether); dried in vac.; elem. anal.;
DOI:10.1016/S0277-5387(00)86058-1
