Technology Process of Anthracene, 1,2,3,4,5,6,7,8-octahydro-9-phenyl-
There total 3 articles about Anthracene, 1,2,3,4,5,6,7,8-octahydro-9-phenyl- which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
methylmagnesium bromide; hydrogen; cobalt acetylacetonate; 1,3-bis[2,6-diisopropylphenyl]imidazolium chloride;
In
tetrahydrofuran;
at 20 ℃;
for 8h;
under 60006 Torr;
Cooling with ice;
- Guidance literature:
-
With
hydrogen;
tetra-n-propyl-diborane;
at 180 ℃;
for 1h;
under 67505.4 Torr;
Title compound not separated from byproducts;
- Guidance literature:
-
Multi-step reaction with 2 steps
1: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / toluene; ethanol / 24 h / Inert atmosphere; Reflux; Sealed tube
2: methylmagnesium bromide; tetrahydrofuran; cobalt acetylacetonate; 1,3-bis[2,6-diisopropylphenyl]imidazolium chloride; hydrogen / 48 h / 0 - 20 °C / 60006 Torr / Autoclave
With
tetrahydrofuran; tetrakis(triphenylphosphine) palladium(0); methylmagnesium bromide; hydrogen; potassium carbonate; cobalt acetylacetonate; 1,3-bis[2,6-diisopropylphenyl]imidazolium chloride;
In
ethanol; toluene;
DOI:10.1021/jacs.9b03328
