Dimethyl 2,5-dimethylhex-2-enedioate

Base Information

Chemical Name:Dimethyl 2,5-dimethylhex-2-enedioate
CAS No.:19550-59-5
Molecular Formula:C10H16O4
Molecular Weight:200.2316
Hs Code.:
NSC Number:157584
Nikkaji Number:J2.837.363E,J2.881.556E
Mol file:19550-59-5.mol

Synonyms:dimethyl 2,5-dimethylhex-2-enedioate;19550-59-5;2-Hexenedioic acid, 2,5-dimethyl-, dimethyl ester;NSC157584;dimethyl (E)-2,5-dimethylhex-2-enedioate;SCHEMBL11124710;ZXXDDSPXEBOXDR-FNORWQNLSA-N;NSC-157584;2,5-Dimethyl-2-hexenedioic acid dimethyl ester;Dimethyl (2E)-2,5-dimethyl-2-hexenedioate #;(E)-2,5-Dimethyl-2-hexenedioic acid dimethyl ester;(E)-2,5-dimethyl-hex-2-enedioic acid dimethyl ester

Suppliers and Price of Dimethyl 2,5-dimethylhex-2-enedioate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 4 raw suppliers

Chemical Property of Dimethyl 2,5-dimethylhex-2-enedioate

Chemical Property:

Vapor Pressure:0.0443mmHg at 25°C
Boiling Point:237.6°Cat760mmHg
Flash Point:106.6°C
Density:1.03g/cm³
XLogP3:1.6
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:6
Exact Mass:200.10485899
Heavy Atom Count:14
Complexity:243

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(CC=C(C)C(=O)OC)C(=O)OC
Isomeric SMILES:CC(C/C=C(\C)/C(=O)OC)C(=O)OC

Technology Process of Dimethyl 2,5-dimethylhex-2-enedioate

There total 3 articles about Dimethyl 2,5-dimethylhex-2-enedioate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 25.0%

: 97-63-2,9003-42-3
methyl methacrylate

: 80-62-6,114512-63-9,143476-91-9,25188-98-1,9011-14-7
methacrylic acid methyl ester

: 1450925-42-4
C₁₁H₁₈O₄

: 1450925-43-5
2,5-dimethyl-2-hexenedioic acid diethyl ester

: 19550-59-5
2,5-dimethyl-2-hexenedioic acid dimethyl ester

Guidance literature:: methacrylic acid methyl ester; With (1,3,4)-triphenyl-4,5-dihydro-1H-1,2,4-triazol-5-ylidene; In toluene; at 80 ℃; for 1h; Inert atmosphere; Schlenk technique;

methyl methacrylate; In toluene; at 80 ℃; for 4h; Time; Overall yield = 0.22 g; Inert atmosphere; Schlenk technique;
DOI:10.1021/jo401477b

Reference yield:

: 80-62-6,114512-63-9,143476-91-9,25188-98-1,9011-14-7
methacrylic acid methyl ester

: 88598-80-5
2,5-dimethyl-3-hexenedioic acid dimethyl ester

: 19550-59-5
2,5-dimethyl-2-hexenedioic acid dimethyl ester

Guidance literature:: With (1,3,4)-triphenyl-4,5-dihydro-1H-1,2,4-triazol-5-ylidene; phenol; at 80 ℃; for 4h; Reagent/catalyst; Overall yield = 87 %; Overall yield = 87 g;

Reference yield:

: 1663-39-4,25232-27-3
tert-Butyl acrylate

: 80-62-6,114512-63-9,143476-91-9,25188-98-1,9011-14-7
methacrylic acid methyl ester

: 19550-59-5
2,5-dimethyl-2-hexenedioic acid dimethyl ester

: C₁₂H₂₀O₄

: C₁₄H₂₄O₄

Guidance literature:: With (1,3,4)-triphenyl-4,5-dihydro-1H-1,2,4-triazol-5-ylidene; In 1,4-dioxane; Temperature; Solvent; Reflux;
DOI:10.1246/cl.170263