tert-Butylphenyldichlorosilane

Base Information

• Chemical Name: tert-Butylphenyldichlorosilane
• CAS No.: 17887-41-1
• Molecular Formula: C10H14Cl2Si
• Molecular Weight: 233.213
• Hs Code.: 2931900090
• European Community (EC) Number: 241-835-2
• DSSTox Substance ID: DTXSID7066277
• Nikkaji Number: J260.783B
• Wikidata: Q81992869
• Mol file: 17887-41-1.mol

Synonyms:tert-Butylphenyldichlorosilane;17887-41-1;tert-butyl-dichloro-phenylsilane;tert-butyldichloro(phenyl)silane;t-Butylphenyldichlorosilane;Benzene, [dichloro(1,1-dimethylethyl)silyl]-;Silane, tert-butyldichlorophenyl-;Silane, dichloro(1,1-dimethylethyl)phenyl-;Dichloro(1,1-dimethylethyl)phenylsilane;EINECS 241-835-2;Benzene, (dichloro(1,1-dimethylethyl)silyl)-;tert-butyldichlorophenylsilane;SCHEMBL450654;DTXSID7066277;tert-Butyl(dichloro)phenylsilane #;MFCD00051441;BS-43930;B5314;T70448

Chemical Property of tert-Butylphenyldichlorosilane

Chemical Property:

• Vapor Pressure: 0.03mmHg at 25°C
• Refractive Index: 1.5150
• Boiling Point: 252.9 °C at 760 mmHg
• Flash Point: 101.9 °C
• PSA: 0.00000
• Density: 1.08 g/cm³
• LogP: 3.61350
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 2
• Exact Mass: 232.0241824
• Heavy Atom Count: 13
• Complexity: 166

Purity/Quality:

97% ^*data from raw suppliers

tert-Butyldichloro(phenyl)silane ^*data from reagent suppliers

Safty Information:

• Pictogram(s): R34:Causes burns.
• Hazard Codes: R34:Causes burns.
• Statements: 34
• Safety Statements: 26-36/37/39-45

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(C)(C)[Si](C1=CC=CC=C1)(Cl)Cl

Technology Process of tert-Butylphenyldichlorosilane

There total 4 articles about tert-Butylphenyldichlorosilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

Phenyltrichlorosilane (98-13-5) → phenyl-tert-butyldichlorosilane (17887-41-1)

Guidance literature:

With t-C₄H₉Li; In not given;

Reference yield:

tert.-butyl lithium (594-19-4) + Phenyltrichlorosilane (98-13-5) → phenyl-tert-butyldichlorosilane (17887-41-1)

Guidance literature:

DOI:10.1021/ja01633a032

Reference yield:

tert.-butyl lithium (594-19-4) + Phenyltrichlorosilane (98-13-5) → C22H40Si (1609256-70-3) + di-tert-butylphenylsilane (18415-17-3) + phenyl-tert-butyldichlorosilane (17887-41-1) + di-tert-butylchlorophenylsilane (140903-06-6)

Guidance literature:

at 60 ℃; for 4h;

DOI:10.1016/j.inoche.2014.02.039

upstream raw materials:

tert.-butyl lithium

Phenyltrichlorosilane

Downstream raw materials:

(t-bu)phSi(OH)2

(t-bu)phSi(NH₂)2

1,2,3,4-tetra-t-butyl-1,2,3,4-tetraphenylcyclotetrasilane

1-((4aR,6R,7aS)-2-tert-Butyl-2-phenyl-tetrahydro-furo[3,2-d][1,3,2]dioxasilin-6-yl)-5-methyl-1H-pyrimidine-2,4-dione