9-[(4-Methoxyphenyl)ethynyl]-10-[(4-nitrophenyl)ethynyl]anthracene

Base Information

Chemical Name:9-[(4-Methoxyphenyl)ethynyl]-10-[(4-nitrophenyl)ethynyl]anthracene
CAS No.:130073-58-4
Molecular Formula:C₃₁H₁₉NO₃
Molecular Weight:453.497
Hs Code.:
DSSTox Substance ID:DTXSID50561818
Nikkaji Number:J463.312A
Wikidata:Q82445695

Synonyms:130073-58-4;DTXSID50561818;9-[(4-Methoxyphenyl)ethynyl]-10-[(4-nitrophenyl)ethynyl]anthracene;9-(p-methoxyphenylethynyl)-10-(p-nitrophenylethynyl)anthracene

Suppliers and Price of 9-[(4-Methoxyphenyl)ethynyl]-10-[(4-nitrophenyl)ethynyl]anthracene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 2 raw suppliers

Chemical Property of 9-[(4-Methoxyphenyl)ethynyl]-10-[(4-nitrophenyl)ethynyl]anthracene

Chemical Property:

XLogP3:8.3
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:5
Exact Mass:453.13649347
Heavy Atom Count:35
Complexity:840

Purity/Quality:: 99.90% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COC1=CC=C(C=C1)C#CC2=C3C=CC=CC3=C(C4=CC=CC=C42)C#CC5=CC=C(C=C5)[N+](=O)[O-]

Technology Process of 9-[(4-Methoxyphenyl)ethynyl]-10-[(4-nitrophenyl)ethynyl]anthracene

There total 5 articles about 9-[(4-Methoxyphenyl)ethynyl]-10-[(4-nitrophenyl)ethynyl]anthracene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 18.0%

: 136384-83-3
9-[(E)-2-(4-Methoxy-phenyl)-vinyl]-10-[(E)-2-(4-nitro-phenyl)-vinyl]-anthracene

: 130073-58-4
9-(p-Methoxyphenylethynyl)-10-(p-nitrophenylethynyl)-anthracene

Guidance literature:: With potassium tert-butylate; In N,N-dimethyl-formamide; for 0.0833333h; Ambient temperature;
DOI:10.1039/c39910000948

Reference yield:

: 523-27-3
9,10-Dibromoanthracene

: 130073-58-4
9-(p-Methoxyphenylethynyl)-10-(p-nitrophenylethynyl)-anthracene

Guidance literature:: Multi-step reaction with 4 steps

1: 1.54 g / Et₃N, pyridine / Pd(PPh₃)2Cl₂, CuI / 1.5 h

2: 1.41 g / Et₃N / Pd(PPh₃)2Cl₂, CuI / 3 h / 89 °C

3: KOH, dibenzo-18-crown-6 / toluene / 0.25 h / 70 °C

4: Et₃N / Pd(PPh₃)2Cl₂ / benzene / 0.25 h / Heating

With pyridine; potassium hydroxide; dibenzo-18-crown-6; triethylamine; bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; In toluene; benzene;
DOI:10.1007/BF00962407

Reference yield:

: 130049-18-2
9-bromo-10-(3-hydroxy-3-methylbutyn-1-yl)anthracene

: 130073-58-4
9-(p-Methoxyphenylethynyl)-10-(p-nitrophenylethynyl)-anthracene

Guidance literature:: Multi-step reaction with 3 steps

1: 1.41 g / Et₃N / Pd(PPh₃)2Cl₂, CuI / 3 h / 89 °C

2: KOH, dibenzo-18-crown-6 / toluene / 0.25 h / 70 °C

3: Et₃N / Pd(PPh₃)2Cl₂ / benzene / 0.25 h / Heating

With potassium hydroxide; dibenzo-18-crown-6; triethylamine; bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; In toluene; benzene;
DOI:10.1007/BF00962407