1,2-Epoxy-9-decene

Base Information

• Chemical Name: 1,2-Epoxy-9-decene
• CAS No.: 85721-25-1
• Molecular Formula: C10H18O
• Molecular Weight: 154.252
• Hs Code.: 29109000
• European Community (EC) Number: 288-437-5
• UNII: D2A752E1N5
• DSSTox Substance ID: DTXSID701006337
• Nikkaji Number: J256.544G
• Mol file: 85721-25-1.mol

Synonyms:1,2-Epoxy-9-decene;85721-25-1;2-oct-7-enyloxirane;Oxirane, (7-octenyl)-;Oct-7-enyloxirane;(7-Octenyl)oxirane;2-(oct-7-en-1-yl)oxirane;D2A752E1N5;EINECS 288-437-5;2-(7-octen-1-yl)Oxirane;2-(7-Octenyl)oxirane;2-(oct-7-enyl)oxirane;2-(7-Octenyl)oxirane #;SCHEMBL143336;UNII-D2A752E1N5;1,2-Epoxy-9-decene, 96%;9,10-EPOXY-1-DECENE;DTXSID701006337;MFCD00069427;AKOS005254627;MS-20920;CS-0358861;E0411;FT-0606444;FT-0773635;D90507;J-640008;J-800008

Chemical Property of 1,2-Epoxy-9-decene

Chemical Property:

• Appearance/Colour: clear colorless liquid
• Vapor Pressure: 0.474mmHg at 25°C
• Melting Point: 25 °C
• Refractive Index: n20/D 1.442(lit.)
• Boiling Point: 199.8 °C at 760 mmHg
• Flash Point: 68.8 °C
• PSA: 12.53000
• Density: 0.876 g/cm³
• LogP: 2.91180
• Storage Temp.: 0-6°C
• Sensitive.: Moisture Sensitive
• XLogP3: 3.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 7
• Exact Mass: 154.135765193
• Heavy Atom Count: 11
• Complexity: 109

Purity/Quality:

98% ^*data from raw suppliers

1,2-Epoxy-9-decene ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 37/38-41
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C=CCCCCCCC1CO1

Technology Process of 1,2-Epoxy-9-decene

There total 5 articles about 1,2-Epoxy-9-decene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

1,10-decadiene (1647-16-1) → 2-(oct-7-en-1-yl)oxirane (85721-25-1)

Guidance literature:

With oxygen; In acetonitrile; at 60 ℃; for 1.5h; under 760.051 Torr; chemoselective reaction; Catalytic behavior;

DOI:10.1007/s11164-017-3027-z

Reference yield: 29.0%

rac/meso-1,2,9,10-diepoxydecane (24854-67-9) + 1,10-decadiene (1647-16-1) → diepoxydecane + 2-(oct-7-en-1-yl)oxirane (85721-25-1)

Guidance literature:

With dihydrogen peroxide; In (C₃₇H₇₈N)3PW₄O₂₄; dichloromethane; water;

Reference yield: 23.0%

9-(oxiran-2-yl)nonanoic acid (2443-41-6) → 1,2-Epoxydecane (2404-44-6) + 2-(oct-7-en-1-yl)oxirane (85721-25-1) + 1,2;19,20-diepoxyicosane

Guidance literature:

With potassium methanolate; In methanol; at 40 - 45 ℃; Yield given; electrolysis: anode: platinum foil; current source: galvanostat; current density 200 mA cm^-2; current consumption: 2.3 F mol^-1; cell voltage 50-70 V;

DOI:10.3891/acta.chem.scand.52-0672

upstream raw materials:

9-(oxiran-2-yl)nonanoic acid

1,10-decadiene

10-undecenoic acid

rac/meso-1,2,9,10-diepoxydecane

Downstream raw materials:

1,2-Epoxydecane

3-hydroxysebacic acid

2-(phenylseleno)-9-(decene)-1-ol

1-(4-tolyl)thio-dec-9-en-2-ol

Refernces

• 1、 Kazemnejadi, Milad,Shakeri, Alireza,Nikookar, Mahsa,Mohammadi, Mohammad,Esmaeilpour, Mohsen. "Co(II) Schiff base complex decorated on polysalicylaldehyde as an efficient, selective, heterogeneous and reusable catalyst for epoxidation of olefins in mild and self-coreductant conditions". . p. 6889 - 6910. Retrieved 2017/10/05.
• 2、 Alt, Helmut G.,Jung, Michael. "C2-bridged metallocene dichloride complexes of the types (C13H8-CH2CHR-C9H 6-nR′n)ZrCl2 and (C13H8-CH2CHR-C13H 8)MCl2 (n=0, 1; R=H, alkenyl; R′=alkenyl, benzyl; M=Zr, Hf) as self-immobilizing catalyst precursors for ethylene polymerization". . p. 1 - 16. Retrieved 2007/10/03.