Methyl(phenyl)phosphinothioic chloride

Base Information

• Chemical Name: Methyl(phenyl)phosphinothioic chloride
• CAS No.: 13639-62-8
• Molecular Formula: C7H8ClPS
• Molecular Weight: 190.633
• DSSTox Substance ID: DTXSID20504257
• Mol file: 13639-62-8.mol

Synonyms:Methyl(phenyl)phosphinothioic chloride;Phosphinothioic chloride, methylphenyl-;13639-62-8;SCHEMBL21557205;DTXSID20504257

Chemical Property of Methyl(phenyl)phosphinothioic chloride

Chemical Property:

• XLogP3: 3.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 1
• Exact Mass: 189.9772861
• Heavy Atom Count: 10
• Complexity: 152

Purity/Quality:

99.90% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CP(=S)(C1=CC=CC=C1)Cl

Technology Process of Methyl(phenyl)phosphinothioic chloride

There total 3 articles about Methyl(phenyl)phosphinothioic chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

meso-1,2-dimethyl-1,2-diphenyldiphosphine disulfide (3619-83-8) → chloromethylphenylphosphine sulfide (13639-62-8)

Guidance literature:

With sulfuryl dichloride; In toluene; 1.) 23 deg C, 1.5 h, 2.) 60 deg C, 1 h;

DOI:10.1021/ja00389a026

Reference yield:

Tetramethylblei-(IV) (75-74-1) + phenylthiophosphonic acid dichloride (3497-00-5) → chloromethylphenylphosphine sulfide (13639-62-8)

Guidance literature:

In toluene;

Reference yield:

→ chloromethylphenylphosphine sulfide (13639-62-8)

Guidance literature:

1,2-Dimethyl-1,2-diphenyl-diphosphin-disulfid 1) SOCl2, CCl4 2) Cl2, CCl4;

upstream raw materials:

meso-1,2-dimethyl-1,2-diphenyldiphosphine disulfide

Tetramethylblei-(IV)

phenylthiophosphonic acid dichloride

Downstream raw materials:

p-bromophenyl ester of methylphenylthionephosphinic acid

Methylphenyl-thiophosphinsaere-diethylamid

trimethyltin methylphenylthiophosphinate

ethylmethylphenylphosphine oxide