Benzenemethanamine, N-[1-(2-propenyl)cyclopentyl]-

Base Information

• Chemical Name: Benzenemethanamine, N-[1-(2-propenyl)cyclopentyl]-
• CAS No.: 136936-07-7
• Molecular Formula: C15H21N
• Molecular Weight: 215.338
• DSSTox Substance ID: DTXSID60362015
• Nikkaji Number: J1.531.105C
• Wikidata: Q82144707
• Mol file: 136936-07-7.mol

Synonyms:Benzenemethanamine, N-[1-(2-propenyl)cyclopentyl]-;136936-07-7;Cambridge id 5663397;Oprea1_047655;Oprea1_058249;N-Benzyl-1-allylcyclopentanamine;DTXSID60362015;AKOS000566178;AB00092358-01;N-BENZYL-1-(PROP-2-EN-1-YL)CYCLOPENTAN-1-AMINE

Chemical Property of Benzenemethanamine, N-[1-(2-propenyl)cyclopentyl]-

Chemical Property:

• XLogP3: 3.5
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 5
• Exact Mass: 215.167399674
• Heavy Atom Count: 16
• Complexity: 210

Purity/Quality:

99.90% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C=CCC1(CCCC1)NCC2=CC=CC=C2

Technology Process of Benzenemethanamine, N-[1-(2-propenyl)cyclopentyl]-

There total 5 articles about Benzenemethanamine, N-[1-(2-propenyl)cyclopentyl]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 54.0%

N-cyclopentylidene-1-phenylmethanamine (15814-19-4) + allylmagnesium bromide (1730-25-2) → 1-allyl-1-N-benzylaminocyclopentane (136936-07-7)

Guidance literature:

In diethyl ether; for 2h; Heating;

Reference yield: 40.0%

N-cyclopentylidene-1-phenylmethanamine (15814-19-4) + allyl bromide (106-95-6) → 1-allyl-1-N-benzylaminocyclopentane (136936-07-7)

Guidance literature:

allyl bromide; With magnesium; In diethyl ether;

N-cyclopentylidene-1-phenylmethanamine; In diethyl ether; at 20 ℃; for 1h;

DOI:10.1055/s-2002-25770

Reference yield:

cyclopentanone (120-92-3) → 1-allyl-1-N-benzylaminocyclopentane (136936-07-7)

Guidance literature:

Multi-step reaction with 2 steps

1: 54 percent / diethyl ether / 2 h / Heating

In diethyl ether;

upstream raw materials:

N-cyclopentylidene-1-phenylmethanamine

allylmagnesium bromide

allyl bromide

cyclopentanone

Downstream raw materials:

(7R,9R)-7-Phenyl-6-aza-spiro[4.5]decan-9-ol

C₁₅H₁₉NO

1,2,4,5-tetrahydro-3H-5-methylspiro

Refernces

• 1、 Kuznetsov, V. V.,Lantsetov, S. V.,Aliev, A. E.,Varlamov, A. V.,Prostakov, N. S.. "SYNTHESIS OF METHYL-SUBSTITUTED 1,2,4,5-TETRAHYDRO-3H-SPIRO". . p. 61 - 65. Retrieved 2007/10/02.