Benzene, 1,4-bis(hexadecyloxy)-

Base Information

• Chemical Name: Benzene, 1,4-bis(hexadecyloxy)-
• CAS No.: 137436-24-9
• Molecular Formula: C38H70O2
• Molecular Weight: 558.973
• DSSTox Substance ID: DTXSID50478497
• Wikidata: Q82311922
• Mol file: 137436-24-9.mol

Synonyms:Benzene, 1,4-bis(hexadecyloxy)-;137436-24-9;SCHEMBL6932555;DTXSID50478497

Chemical Property of Benzene, 1,4-bis(hexadecyloxy)-

Chemical Property:

• XLogP3: 17.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 32
• Exact Mass: 558.53758147
• Heavy Atom Count: 40
• Complexity: 414

Purity/Quality:

99.90% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCCCCCCCCCCCCOC1=CC=C(C=C1)OCCCCCCCCCCCCCCCC

Technology Process of Benzene, 1,4-bis(hexadecyloxy)-

There total 6 articles about Benzene, 1,4-bis(hexadecyloxy)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.1%

hydroquinone (123-31-9,8027-02-9) + hexadecanyl bromide (112-82-3) → 4,4'-di-n-hexadecyloxybenzene (137436-24-9)

Guidance literature:

With potassium carbonate; In acetone; Heating / reflux;

Reference yield: 76.0%

p-benzoquinone (106-51-4) + hexadecanyl bromide (112-82-3) → 4,4'-di-n-hexadecyloxybenzene (137436-24-9)

Guidance literature:

With potassium carbonate; In acetone; for 120h; Heating;

DOI:10.1021/j100014a003

Reference yield:

hydroquinone (123-31-9,8027-02-9) + hexadecanyl bromide (112-82-3) → p-(hexadecyloxy)phenol (13037-88-2) + 4,4'-di-n-hexadecyloxybenzene (137436-24-9)

Guidance literature:

With sodium hydride; sodium iodide; In N,N-dimethyl-formamide; Ambient temperature;

DOI:10.1021/jm00087a023

upstream raw materials:

tosylate de n-hexadecyle

sodium 4-hydroxybenzen-1-olate

hydroquinone

hexadecanyl bromide

Downstream raw materials:

1,4-diodo-2,5-bis(n-hexadecyloxy)benzene

1,4-bis(hexadecyloxy)-2,5-divinylbenzene

1,4-bis(ethynyl)-2,5-di(hexadecyloxy)benzene

(2,5-bis(hexadecyloxy)-1,4-phenylene)bis(ethyne-2,1-diyl)bis(trimethylsilane)