S-(4-methylphenyl) 4-nitrobenzenesulfonothioate

Base Information

• Chemical Name: S-(4-methylphenyl) 4-nitrobenzenesulfonothioate
• CAS No.: 94583-15-0
• Molecular Formula: C13H11NO4S2
• Molecular Weight: 309.367
• Mol file: 94583-15-0.mol

Synonyms:

Chemical Property of S-(4-methylphenyl) 4-nitrobenzenesulfonothioate

Chemical Property:

• Vapor Pressure: 1.33E-09mmHg at 25°C
• Boiling Point: 499°C at 760 mmHg
• Flash Point: 255.6°C
• Density: 1.46g/cm³

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of S-(4-methylphenyl) 4-nitrobenzenesulfonothioate

There total 10 articles about S-(4-methylphenyl) 4-nitrobenzenesulfonothioate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

4-nitrobenzenesulfonohydrazide (2937-05-5) + para-thiocresol (106-45-6) → S-(p-tolyl) 4-nitrobenzenesulfonothioate (94583-15-0)

Guidance literature:

With tert.-butylhydroperoxide; sodium iodide; In acetonitrile; at 25 ℃; for 8h;

Reference yield: 77.0%

1-[(4-methylphenyl)sulfanyl]pyrrolidine-2,5-dione (39549-10-5) + sodium 4-nitrobenzenesulfinate (15959-31-6) → S-(p-tolyl) 4-nitrobenzenesulfonothioate (94583-15-0)

Guidance literature:

With scandium tris(trifluoromethanesulfonate); In water; at 30 ℃; for 6h; Ionic liquid;

DOI:10.1016/j.tetlet.2012.09.132

Reference yield: 68.0%

p-nitrophenyl p-nitrobenzenethiosulfonate (1041-15-2) + 1-[(diethylamino)sulfanyl]-4-methylbenzol (24398-14-9) → S-(p-tolyl) 4-nitrobenzenesulfonothioate (94583-15-0)

Guidance literature:

In benzene; for 12h; Heating;

upstream raw materials:

p-nitrophenyl p-nitrobenzenethiosulfonate

1-[(diethylamino)sulfanyl]-4-methylbenzol

ethyl p-nitrobenzenethiosulfonate

4-Nitro-benzenethiosulfonic acid S-(2,4-dinitro-phenyl) ester

Refernces

• 1、 Huang, Cheng-Mi,Li, Jian,Wang, Shun-Yi,Ji, Shun-Jun. "TFA promoted multi-component reaction of aryldiazonium with sodium metabisulphite and thiols: Construction of thiosulfonate under transition-metal free conditions". supporting information. p. 1923 - 1926. Retrieved 2020/01/13.
• 2、 Chen, Qian,Huang, Yulin,Wang, Xiaofeng,Wu, Jiawei,Yu, Guodian. "Metal-free NaI/TBHP-mediated sulfonylation of thiols with sulfonyl hydrazides". . p. 1713 - 1719. Retrieved 2018/03/21.