Oxocane, 3-ethenyl-6-(phenylsulfonyl)-, cis-

Base Information

Chemical Name:Oxocane, 3-ethenyl-6-(phenylsulfonyl)-, cis-
CAS No.:138035-81-1
Molecular Formula:C₁₅H₂₀O₃S
Molecular Weight:280.388
Hs Code.:
Mol file:138035-81-1.mol

Synonyms:

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Chemical Property of Oxocane, 3-ethenyl-6-(phenylsulfonyl)-, cis-

Chemical Property:

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Technology Process of Oxocane, 3-ethenyl-6-(phenylsulfonyl)-, cis-

There total 10 articles about Oxocane, 3-ethenyl-6-(phenylsulfonyl)-, cis- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 3238-98-0
3-phenylthio-1-bromopropane

: 138035-81-1,138035-89-9
6-phenylsulphonyl-3-vinyloxocane

Guidance literature:: Multi-step reaction with 5 steps

1: 1.) 1.6 M n-BuLi / 1.) toluene, THF, hexane, -30 deg C to r.t., 2.) THF, reflux, 6-7 h

2: 63 percent / H₂ / nickel acetate/sodium borohydride / ethanol / 5-6 h

3: 77 percent / oxone / methanol / 8 h

4: 1.) n-BuLi, hexamethylphosphoric triamide / 1.) THF, hexane, -78 deg C, 1 h, 2.) -78 deg C to -50 deg C, 0.5 h

5: 1 M ethylaluminium dichloride / toluene; hexane / 1.) between -78 deg C and -50 deg C, 5 h, 2.) up to -4 deg C, overnight

With N,N,N,N,N,N-hexamethylphosphoric triamide; Oxone; n-butyllithium; hydrogen; ethylaluminum dichloride; sodium tetrahydroborate; nickel diacetate; In methanol; ethanol; hexane; toluene;
DOI:10.1016/S0040-4020(01)88293-4

Reference yield:

: 3238-98-0
3-phenylthio-1-bromopropane

: 138035-81-1,138035-89-9
6-phenylsulphonyl-3-vinyloxocane

Guidance literature:: Multi-step reaction with 5 steps

1: 1.) 1.6 M n-BuLi / 1.) toluene, THF, hexane, -30 deg C to r.t., 2.) THF, reflux, 6-7 h

2: 63 percent / H₂ / nickel acetate/sodium borohydride / ethanol / 5-6 h

3: 77 percent / oxone / methanol / 8 h

4: 1.) n-BuLi, hexamethylphosphoric triamide / 1.) THF, hexane, -78 deg C, 1 h, 2.) -78 deg C to -50 deg C, 0.5 h

5: 1 M ethylaluminium dichloride / toluene; hexane / 1.) between -78 deg C and -50 deg C, 5 h, 2.) up to -4 deg C, overnight

With N,N,N,N,N,N-hexamethylphosphoric triamide; Oxone; n-butyllithium; hydrogen; ethylaluminum dichloride; sodium tetrahydroborate; nickel diacetate; In methanol; ethanol; hexane; toluene;
DOI:10.1016/S0040-4020(01)88293-4

Reference yield:

: 138035-86-6
(Z)-1-phenylthio-6-trimethylsilylhex-4-yne

: 138035-81-1,138035-89-9
6-phenylsulphonyl-3-vinyloxocane

Guidance literature:: Multi-step reaction with 4 steps

1: 63 percent / H₂ / nickel acetate/sodium borohydride / ethanol / 5-6 h

2: 77 percent / oxone / methanol / 8 h

3: 1.) n-BuLi, hexamethylphosphoric triamide / 1.) THF, hexane, -78 deg C, 1 h, 2.) -78 deg C to -50 deg C, 0.5 h

4: 1 M ethylaluminium dichloride / toluene; hexane / 1.) between -78 deg C and -50 deg C, 5 h, 2.) up to -4 deg C, overnight

With N,N,N,N,N,N-hexamethylphosphoric triamide; Oxone; n-butyllithium; hydrogen; ethylaluminum dichloride; sodium tetrahydroborate; nickel diacetate; In methanol; ethanol; hexane; toluene;
DOI:10.1016/S0040-4020(01)88293-4