Technology Process of Octanedioic acid, 4-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-, 8-methyl
ester, (S)-
There total 8 articles about Octanedioic acid, 4-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-, 8-methyl
ester, (S)- which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
dipyridinium dichromate;
In
N,N-dimethyl-formamide;
for 5h;
Ambient temperature;
DOI:10.1021/jo00029a058
- Guidance literature:
-
Multi-step reaction with 8 steps
1: 80 percent / thionyl chloride, DMF / 12 h / Ambient temperature
2: 1) Mg, 2) CuI / 1) THF, 2) THF, -15 to 0 deg C, 1 h
3: 96 percent / 1 M KOH / methanol / 3 h / Ambient temperature
4: 35 percent / H2O / 48 h / 25 - 28 °C / bakers' yeast, glucose, KH2PO4, MgSO4, 0.1 M KOH (pH 6-7)
5: 94 percent / HCl / 2 h / Ambient temperature
6: 87 percent / imidazole / dimethylformamide / 12 h
7: 1) O3, 2) Ph3P / 1) CH2Cl2, -78 deg C, 2) rt, 12 h
8: 100 percent / pyridinium dichromate / dimethylformamide / 5 h / Ambient temperature
With
1H-imidazole; hydrogenchloride; potassium hydroxide; copper(l) iodide; dipyridinium dichromate; thionyl chloride; ozone; magnesium; N,N-dimethyl-formamide; triphenylphosphine;
In
methanol; water; N,N-dimethyl-formamide;
DOI:10.1021/jo00029a058
- Guidance literature:
-
Multi-step reaction with 7 steps
1: 1) Mg, 2) CuI / 1) THF, 2) THF, -15 to 0 deg C, 1 h
2: 96 percent / 1 M KOH / methanol / 3 h / Ambient temperature
3: 35 percent / H2O / 48 h / 25 - 28 °C / bakers' yeast, glucose, KH2PO4, MgSO4, 0.1 M KOH (pH 6-7)
4: 94 percent / HCl / 2 h / Ambient temperature
5: 87 percent / imidazole / dimethylformamide / 12 h
6: 1) O3, 2) Ph3P / 1) CH2Cl2, -78 deg C, 2) rt, 12 h
7: 100 percent / pyridinium dichromate / dimethylformamide / 5 h / Ambient temperature
With
1H-imidazole; hydrogenchloride; potassium hydroxide; copper(l) iodide; dipyridinium dichromate; ozone; magnesium; triphenylphosphine;
In
methanol; water; N,N-dimethyl-formamide;
DOI:10.1021/jo00029a058
