Ruthenium, carbonylchlorophenylbis(tricyclohexylphosphine)-

Base Information

Chemical Name:Ruthenium, carbonylchlorophenylbis(tricyclohexylphosphine)-
CAS No.:138367-77-8
Molecular Formula:C43H71ClOP2Ru
Molecular Weight:802.507
Hs Code.:

Synonyms:

Suppliers and Price of Ruthenium, carbonylchlorophenylbis(tricyclohexylphosphine)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 4 raw suppliers

Chemical Property of Ruthenium, carbonylchlorophenylbis(tricyclohexylphosphine)-

Chemical Property:

Purity/Quality:: 99.90% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of Ruthenium, carbonylchlorophenylbis(tricyclohexylphosphine)-

There total 3 articles about Ruthenium, carbonylchlorophenylbis(tricyclohexylphosphine)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 109800-33-1
Ru(CO)Cl(HCCHPh)(PPh₃)2

: 2622-14-2
tricyclohexylphosphine

: 138367-77-8
[RuCl(Ph)Cl(CO)(PCy₃)₂]

Guidance literature:: In tetrahydrofuran; for 4h; Solvent; Inert atmosphere; Schlenk technique; Glovebox; Reflux;
DOI:10.1039/c8dt04278k

Reference yield: 74.0%

: Grubbs catalyst first generation

: 138367-77-8
[RuCl(Ph)Cl(CO)(PCy₃)₂]

Guidance literature:: With oxygen; In neat (no solvent); High Pressure; pressurizing of a powdered complex in the autoclave with oxygen (40 bar), heating the autoclave at 60°C for 18 h; venting the oxygen off, washing the solid with methanol and pentane;
DOI:10.1021/om0208218

Reference yield:

: Grubbs catalyst first generation

: 138367-77-8
[RuCl(Ph)Cl(CO)(PCy₃)₂]

: Ru(II)Cl₂(PCy₃)2(benzaldehyde)

Guidance literature:: With mesoporous silica; In CH₂Cl₂; byproducts: P(C6H11)3; (N2, Schlenk technique); addn. of CH2Cl2 soln. of ruthenium compd. to mesoporous silica; washing silica with CH2Cl2, extn. (CH2Cl2) in Soxhlet apparatus, chromy., NMR, MS and EDX;
DOI:10.1039/b911795b