Bis(benzyloxy)(chloromethyl)methylsilane

Base Information

Chemical Name:Bis(benzyloxy)(chloromethyl)methylsilane
CAS No.:138380-14-0
Molecular Formula:C16H19ClO2Si
Molecular Weight:306.864
Hs Code.:
DSSTox Substance ID:DTXSID70569275
Wikidata:Q82456392

Synonyms:138380-14-0;Bis(benzyloxy)(chloromethyl)methylsilane;DTXSID70569275

Suppliers and Price of Bis(benzyloxy)(chloromethyl)methylsilane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 1 raw suppliers

Chemical Property of Bis(benzyloxy)(chloromethyl)methylsilane

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:7
Exact Mass:306.0842841
Heavy Atom Count:20
Complexity:241

Purity/Quality:: 99.90% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C[Si](CCl)(OCC1=CC=CC=C1)OCC2=CC=CC=C2

Technology Process of Bis(benzyloxy)(chloromethyl)methylsilane

There total 1 articles about Bis(benzyloxy)(chloromethyl)methylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 100-51-6,185532-71-2
benzyl alcohol

: 1558-33-4
chloromethylmethyldichlorosilane

: 138380-14-0
(chloromethyl)bis(benzyloxy)methylsilane

Guidance literature:: In pentane; 1) 0 deg C, 3 h 2) 23 deg C, 7 h;
DOI:10.1002/hlca.19910740712

Reference yield:

: 138380-14-0
(chloromethyl)bis(benzyloxy)methylsilane

: 100-51-6,185532-71-2
benzyl alcohol

: 61214-13-9
methyltris(benzyloxy)silane

: 138380-16-2
bis(benzyloxy)<(benzyloxy)methyl>methylsilane

Guidance literature:: With sodium hydride; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts; 1) THF, 23 deg C, 3 h 2) 23 deg C, 6 h;
DOI:10.1002/hlca.19910740712

Reference yield:

: 138380-14-0
(chloromethyl)bis(benzyloxy)methylsilane

: 138380-25-3
<(benzyloxy)methyl>(tert-butyl)(1-ethoxyethenyl)methylsilane

Guidance literature:: Multi-step reaction with 5 steps

1: 1) NaH / 1) THF, 23 deg C, 3 h 2) 23 deg C, 6 h

2: diethyl ether; pentane / 0.5 h / 0 °C

3: LiAlH₄ / diethyl ether; pentane / 4.5 h

4: 92 percent / Cl₂ / CCl₄ / -30 °C

5: 1) t-BuLi / 1a) THF, pentane, -78 to 0 deg C, 1b) 0 deg C, 5 min 2) -78 deg C to 0 deg C, 2 h

With lithium aluminium tetrahydride; tert.-butyl lithium; chlorine; sodium hydride; In tetrachloromethane; diethyl ether; pentane;
DOI:10.1002/hlca.19910740712