Benzenemethanol, 2-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-a-[3-[[(1,1-dimethylethyl)dimethyl silyl]oxy]-2-(ethylthio)-2-butenyl]-, (S)-

Base Information

• Chemical Name: Benzenemethanol, 2-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-a-[3-[[(1,1-dimethylethyl)dimethyl silyl]oxy]-2-(ethylthio)-2-butenyl]-, (S)-
• CAS No.: 141192-28-1
• Molecular Formula: C₂₅H₄₆O₃SSi₂
• Molecular Weight: 482.875
• Mol file: 141192-28-1.mol

Synonyms:

Chemical Property of Benzenemethanol, 2-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-a-[3-[[(1,1-dimethylethyl)dimethyl silyl]oxy]-2-(ethylthio)-2-butenyl]-, (S)-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Benzenemethanol, 2-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-a-[3-[[(1,1-dimethylethyl)dimethyl silyl]oxy]-2-(ethylthio)-2-butenyl]-, (S)-

There total 1 articles about Benzenemethanol, 2-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-a-[3-[[(1,1-dimethylethyl)dimethyl silyl]oxy]-2-(ethylthio)-2-butenyl]-, (S)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

tert-Butyl-((S)-2-ethylsulfanyl-1-methyl-allyloxy)-dimethyl-silane (141192-22-5) + 2-((tert-butyldimethylsilyl)oxy)benzaldehyde (116585-12-7) → (Z)-(S)-4-(tert-Butyl-dimethyl-silanyloxy)-1-[2-(tert-butyl-dimethyl-silanyloxy)-phenyl]-3-ethylsulfanyl-pent-3-en-1-ol (141192-28-1)

Guidance literature:

In hexane; dichloromethane; at -78 ℃; for 12h; other aldehydes, other chiral allylsilyl ether;

DOI:10.1016/S0040-4039(00)91616-2

upstream raw materials:

tert-Butyl-((S)-2-ethylsulfanyl-1-methyl-allyloxy)-dimethyl-silane

2-((tert-butyldimethylsilyl)oxy)benzaldehyde